Advanced Degradation of Lignin from Palm Oil Mill Effluent (POME) by a Combination of Photocatalytic-Fenton Treatment and TiO2 Nanoparticle as the Catalyst

Osi Arutanti; Ajeng Arum Sari; Anita Berkah; Muhammad Nurdin; Muhammad Arifuddin Fitriady; Yusnita Parmawati; Nino Rinaldi; Adhi Yuniarto; Tony Hadibarata

doi:10.1007/s11270-020-04617-8

Advanced Degradation of Lignin from Palm Oil Mill Effluent (POME) by a Combination of Photocatalytic-Fenton Treatment and TiO₂ Nanoparticle as the Catalyst

Osi Arutanti^*, Ajeng Arum Sari, Anita Berkah, Muhammad Nurdin, Muhammad Arifuddin Fitriady, Yusnita Parmawati, Nino Rinaldi, Adhi Yuniarto, Tony Hadibarata

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Lignin-based black liquor from oil palm empty fruit bunches (OPEFB) as a side product of the pretreatment process in second-generation bioethanol is the next problem in developing renewable energy. Therefore, developing technology to overcome this problem is needed. In this study, titanium dioxide (TiO₂) as photocatalyst and their synergy with heterogeneous Fenton-like process for degrading lignin was investigated. Several conditions were varied and investigated independently to obtain the optimum condition. Result showed that among the conditions has the optimum number. 0.5 g of FeSO₄, 400 mg/L of H₂O₂, pH 4, and 0.03 g of TiO₂ were the optimum condition of heterogeneous photo-Fenton to decompose 100 ppm of Lignin up to 90% under UV-A irradiation. Post annealing treatment of the prepared TiO₂ improved the photodegradation around 50%. The schematic illustration of lignin photodecomposition also supported the results.

Original language	English
Article number	266
Journal	Water, Air, and Soil Pollution
Volume	231
Issue number	6
DOIs	https://doi.org/10.1007/s11270-020-04617-8
Publication status	Published - 1 Jun 2020

Keywords

Black liquor
Heterogeneous photocatalytic
Photo-Fenton
Photodecomposition

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1007/s11270-020-04617-8

Cite this

Arutanti, O., Sari, A. A., Berkah, A., Nurdin, M., Fitriady, M. A., Parmawati, Y., Rinaldi, N., Yuniarto, A., & Hadibarata, T. (2020). Advanced Degradation of Lignin from Palm Oil Mill Effluent (POME) by a Combination of Photocatalytic-Fenton Treatment and TiO₂ Nanoparticle as the Catalyst. Water, Air, and Soil Pollution, 231(6), Article 266. https://doi.org/10.1007/s11270-020-04617-8

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title = "Advanced Degradation of Lignin from Palm Oil Mill Effluent (POME) by a Combination of Photocatalytic-Fenton Treatment and TiO2 Nanoparticle as the Catalyst",

abstract = "Lignin-based black liquor from oil palm empty fruit bunches (OPEFB) as a side product of the pretreatment process in second-generation bioethanol is the next problem in developing renewable energy. Therefore, developing technology to overcome this problem is needed. In this study, titanium dioxide (TiO2) as photocatalyst and their synergy with heterogeneous Fenton-like process for degrading lignin was investigated. Several conditions were varied and investigated independently to obtain the optimum condition. Result showed that among the conditions has the optimum number. 0.5 g of FeSO4, 400 mg/L of H2O2, pH 4, and 0.03 g of TiO2 were the optimum condition of heterogeneous photo-Fenton to decompose 100 ppm of Lignin up to 90% under UV-A irradiation. Post annealing treatment of the prepared TiO2 improved the photodegradation around 50%. The schematic illustration of lignin photodecomposition also supported the results.",

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author = "Osi Arutanti and Sari, {Ajeng Arum} and Anita Berkah and Muhammad Nurdin and Fitriady, {Muhammad Arifuddin} and Yusnita Parmawati and Nino Rinaldi and Adhi Yuniarto and Tony Hadibarata",

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Arutanti, O, Sari, AA, Berkah, A, Nurdin, M, Fitriady, MA, Parmawati, Y, Rinaldi, N, Yuniarto, A & Hadibarata, T 2020, 'Advanced Degradation of Lignin from Palm Oil Mill Effluent (POME) by a Combination of Photocatalytic-Fenton Treatment and TiO₂ Nanoparticle as the Catalyst', Water, Air, and Soil Pollution, vol. 231, no. 6, 266. https://doi.org/10.1007/s11270-020-04617-8

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AU - Arutanti, Osi

AU - Sari, Ajeng Arum

AU - Berkah, Anita

AU - Nurdin, Muhammad

AU - Fitriady, Muhammad Arifuddin

AU - Parmawati, Yusnita

AU - Rinaldi, Nino

AU - Yuniarto, Adhi

AU - Hadibarata, Tony

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Lignin-based black liquor from oil palm empty fruit bunches (OPEFB) as a side product of the pretreatment process in second-generation bioethanol is the next problem in developing renewable energy. Therefore, developing technology to overcome this problem is needed. In this study, titanium dioxide (TiO2) as photocatalyst and their synergy with heterogeneous Fenton-like process for degrading lignin was investigated. Several conditions were varied and investigated independently to obtain the optimum condition. Result showed that among the conditions has the optimum number. 0.5 g of FeSO4, 400 mg/L of H2O2, pH 4, and 0.03 g of TiO2 were the optimum condition of heterogeneous photo-Fenton to decompose 100 ppm of Lignin up to 90% under UV-A irradiation. Post annealing treatment of the prepared TiO2 improved the photodegradation around 50%. The schematic illustration of lignin photodecomposition also supported the results.

AB - Lignin-based black liquor from oil palm empty fruit bunches (OPEFB) as a side product of the pretreatment process in second-generation bioethanol is the next problem in developing renewable energy. Therefore, developing technology to overcome this problem is needed. In this study, titanium dioxide (TiO2) as photocatalyst and their synergy with heterogeneous Fenton-like process for degrading lignin was investigated. Several conditions were varied and investigated independently to obtain the optimum condition. Result showed that among the conditions has the optimum number. 0.5 g of FeSO4, 400 mg/L of H2O2, pH 4, and 0.03 g of TiO2 were the optimum condition of heterogeneous photo-Fenton to decompose 100 ppm of Lignin up to 90% under UV-A irradiation. Post annealing treatment of the prepared TiO2 improved the photodegradation around 50%. The schematic illustration of lignin photodecomposition also supported the results.

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