Capacity retention of lithium sulfur batteries enhanced with nano-sized TiO2-embedded polyethylene oxide

Felix Lee, Meng Che Tsai, Ming Hsien Lin, Yatim Lailun Ni'mah, Sunny Hy, Chao Yen Kuo, Ju Hsiang Cheng, John Rick, Wei Nien Su*, Bing Joe Hwang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

68 Citations (Scopus)

Abstract

The shuttle effect of polysulfides in Li/S batteries causes the loss of active materials and capacity decay. This phenomenon has retarded the practical application of Li/S batteries. Herein, we demonstrate that the undesired shuttle mechanism owing to dissolved lithium polysulfides can be effectively suppressed by the incorporation of TiO2 nanoparticles (NPs) within a solid nanocomposite polymer electrolyte of polyethylene oxide (PEO). The approach shows enhanced capacity retention, whereby a cell with a hybrid solid electrolyte of TiO2 NPs embedded in PEO has delivered more than 1450 mA h g−1 (first cycle discharge capacity) with ∼87% capacity retention after 100 cycles, compared to only 38% capacity retention in the absence of TiO2. Density Functional Theory (DFT) computational results based on bonding interactions and Raman characterization of the different components reveal that the undesired diffusion shuttle mechanism causing Li anode passivation can be effectively reduced by the use of nano-sized TiO2 and polyethylene oxide.

Original languageEnglish
Pages (from-to)6708-6715
Number of pages8
JournalJournal of Materials Chemistry A
Volume5
Issue number14
DOIs
Publication statusPublished - 2017
Externally publishedYes

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