TY - JOUR
T1 - Catalytic hydrocracking of Kapuk seed oil (Ceiba pentandra) to produce biofuel using Zn-Mo supported HZSM-5 catalyst
AU - Mirzayanti, Y. W.
AU - Prajitno, D. H.
AU - Roesyadi, A.
N1 - Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2017/6/1
Y1 - 2017/6/1
N2 - In the present paper Kapuk seed oil (KSO) was considered as a potential biofuel for alternative fuel from inedible oil. Catalytic hydrocracking of Kapuk seed oil using Zn-Mo supported on the HZSM-5 catalyst in a slurry pressure batch reactor at various temperature with reactor pressure in range 10-15 bar. The Zn-Mo/HZSM-5 catalyst was prepared by incipient wetness impregnation. The physicochemical properties of the catalyst were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) method. The best catalyst performance on catalytic hydrocracking of KSO using Zn-Mo/HZSM-5 (Si/Al = 25) with loading 2.92%wt for Zn and 7.55%wt for Mo. It displayed the highest hydrocarbon content decarboxylation and/or decarbonylation were 35.51 area% of n-paraffins and the highest content for gasoil-range alkanes was 17.24 area% at 4000C. The liquid product predominant is n-C15, and the second component is n-C17. The catalyst Zn-Mo/HZSM-5 was helpful for the catalytic hydrocracking of KSO for hydrocarbon biofuel production.
AB - In the present paper Kapuk seed oil (KSO) was considered as a potential biofuel for alternative fuel from inedible oil. Catalytic hydrocracking of Kapuk seed oil using Zn-Mo supported on the HZSM-5 catalyst in a slurry pressure batch reactor at various temperature with reactor pressure in range 10-15 bar. The Zn-Mo/HZSM-5 catalyst was prepared by incipient wetness impregnation. The physicochemical properties of the catalyst were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) method. The best catalyst performance on catalytic hydrocracking of KSO using Zn-Mo/HZSM-5 (Si/Al = 25) with loading 2.92%wt for Zn and 7.55%wt for Mo. It displayed the highest hydrocarbon content decarboxylation and/or decarbonylation were 35.51 area% of n-paraffins and the highest content for gasoil-range alkanes was 17.24 area% at 4000C. The liquid product predominant is n-C15, and the second component is n-C17. The catalyst Zn-Mo/HZSM-5 was helpful for the catalytic hydrocracking of KSO for hydrocarbon biofuel production.
UR - http://www.scopus.com/inward/record.url?scp=85020934731&partnerID=8YFLogxK
U2 - 10.1088/1755-1315/67/1/012023
DO - 10.1088/1755-1315/67/1/012023
M3 - Conference article
AN - SCOPUS:85020934731
SN - 1755-1307
VL - 67
JO - IOP Conference Series: Earth and Environmental Science
JF - IOP Conference Series: Earth and Environmental Science
IS - 1
M1 - 012023
T2 - 2017 7th International Conference on Environment and Industrial Innovation, ICEII 2017
Y2 - 24 April 2017 through 26 April 2017
ER -