Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes

Dety Oktavia Sulistiono; Badrut Tamam Ibnu Ali; Alvin Rahmad Widyanto; Ratna Ediati; Nurul Widiastuti; Witri Wahyu Lestari; Syafsir Akhlus; Rendy Muhamad Iqbal; Semuel Pati Senda; Hamzah Fansuri

doi:10.1016/j.cscee.2024.100739

Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes

Dety Oktavia Sulistiono, Badrut Tamam Ibnu Ali, Alvin Rahmad Widyanto, Ratna Ediati, Nurul Widiastuti, Witri Wahyu Lestari, Syafsir Akhlus, Rendy Muhamad Iqbal, Semuel Pati Senda, Hamzah Fansuri^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In response to global clean energy demands, this study develops mixed matrix membranes (MMMs) for gas separation in renewable energy applications. MMMs are produced through phase inversion by employing polysulfone and bimetallic-ZIF (Ni–Co-ZIF-67). Bimetallic-ZIF, formed in-situ by Co and Ni metals in water solvent with triethylamine, enhances gas selectivity. MMMs with 4 wt% bimetallic-ZIF, Co: Ni ratio of 9:1 (4Ni10Z67), exhibit remarkable selectivity: CO₂/CH₄ (21.19), H₂/N₂ (1.47), H₂/CH₄ (44.82), and N₂/CH₄ (30.40). Strong interactions between bimetallic-ZIF and CO₂, facilitated by molecular sieving and Ni–Co sites, contribute to these results.

Original language	English
Article number	100739
Journal	Case Studies in Chemical and Environmental Engineering
Volume	9
DOIs	https://doi.org/10.1016/j.cscee.2024.100739
Publication status	Published - Jun 2024

Keywords

Bimetallic-ZIF
CO capture
Gas emissions
Metal substitution
Renewable energy

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.cscee.2024.100739

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Sulistiono, D. O., Ali, B. T. I., Widyanto, A. R., Ediati, R., Widiastuti, N., Lestari, W. W., Akhlus, S., Iqbal, R. M., Senda, S. P., & Fansuri, H. (2024). Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes. Case Studies in Chemical and Environmental Engineering, 9, Article 100739. https://doi.org/10.1016/j.cscee.2024.100739

@article{697b8d1ca6dc4dc0a040e9a2ba34536d,

title = "Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes",

abstract = "In response to global clean energy demands, this study develops mixed matrix membranes (MMMs) for gas separation in renewable energy applications. MMMs are produced through phase inversion by employing polysulfone and bimetallic-ZIF (Ni–Co-ZIF-67). Bimetallic-ZIF, formed in-situ by Co and Ni metals in water solvent with triethylamine, enhances gas selectivity. MMMs with 4 wt% bimetallic-ZIF, Co: Ni ratio of 9:1 (4Ni10Z67), exhibit remarkable selectivity: CO2/CH4 (21.19), H2/N2 (1.47), H2/CH4 (44.82), and N2/CH4 (30.40). Strong interactions between bimetallic-ZIF and CO2, facilitated by molecular sieving and Ni–Co sites, contribute to these results.",

keywords = "Bimetallic-ZIF, CO capture, Gas emissions, Metal substitution, Renewable energy",

author = "Sulistiono, {Dety Oktavia} and Ali, {Badrut Tamam Ibnu} and Widyanto, {Alvin Rahmad} and Ratna Ediati and Nurul Widiastuti and Lestari, {Witri Wahyu} and Syafsir Akhlus and Iqbal, {Rendy Muhamad} and Senda, {Semuel Pati} and Hamzah Fansuri",

note = "Publisher Copyright: {\textcopyright} 2024 The Authors",

year = "2024",

month = jun,

doi = "10.1016/j.cscee.2024.100739",

language = "English",

volume = "9",

journal = "Case Studies in Chemical and Environmental Engineering",

issn = "2666-0164",

publisher = "Elsevier Ltd.",

}

Sulistiono, DO, Ali, BTI, Widyanto, AR, Ediati, R , Widiastuti, N, Lestari, WW, Akhlus, S, Iqbal, RM, Senda, SP & Fansuri, H 2024, 'Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes', Case Studies in Chemical and Environmental Engineering, vol. 9, 100739. https://doi.org/10.1016/j.cscee.2024.100739

Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes. / Sulistiono, Dety Oktavia; Ali, Badrut Tamam Ibnu; Widyanto, Alvin Rahmad et al.
In: Case Studies in Chemical and Environmental Engineering, Vol. 9, 100739, 06.2024.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crafting the future

T2 - Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes

AU - Sulistiono, Dety Oktavia

AU - Ali, Badrut Tamam Ibnu

AU - Widyanto, Alvin Rahmad

AU - Ediati, Ratna

AU - Widiastuti, Nurul

AU - Lestari, Witri Wahyu

AU - Akhlus, Syafsir

AU - Iqbal, Rendy Muhamad

AU - Senda, Semuel Pati

AU - Fansuri, Hamzah

PY - 2024/6

Y1 - 2024/6

N2 - In response to global clean energy demands, this study develops mixed matrix membranes (MMMs) for gas separation in renewable energy applications. MMMs are produced through phase inversion by employing polysulfone and bimetallic-ZIF (Ni–Co-ZIF-67). Bimetallic-ZIF, formed in-situ by Co and Ni metals in water solvent with triethylamine, enhances gas selectivity. MMMs with 4 wt% bimetallic-ZIF, Co: Ni ratio of 9:1 (4Ni10Z67), exhibit remarkable selectivity: CO2/CH4 (21.19), H2/N2 (1.47), H2/CH4 (44.82), and N2/CH4 (30.40). Strong interactions between bimetallic-ZIF and CO2, facilitated by molecular sieving and Ni–Co sites, contribute to these results.

AB - In response to global clean energy demands, this study develops mixed matrix membranes (MMMs) for gas separation in renewable energy applications. MMMs are produced through phase inversion by employing polysulfone and bimetallic-ZIF (Ni–Co-ZIF-67). Bimetallic-ZIF, formed in-situ by Co and Ni metals in water solvent with triethylamine, enhances gas selectivity. MMMs with 4 wt% bimetallic-ZIF, Co: Ni ratio of 9:1 (4Ni10Z67), exhibit remarkable selectivity: CO2/CH4 (21.19), H2/N2 (1.47), H2/CH4 (44.82), and N2/CH4 (30.40). Strong interactions between bimetallic-ZIF and CO2, facilitated by molecular sieving and Ni–Co sites, contribute to these results.

KW - Bimetallic-ZIF

KW - CO capture

KW - Gas emissions

KW - Metal substitution

KW - Renewable energy

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U2 - 10.1016/j.cscee.2024.100739

DO - 10.1016/j.cscee.2024.100739

M3 - Article

AN - SCOPUS:85191300858

SN - 2666-0164

VL - 9

JO - Case Studies in Chemical and Environmental Engineering

JF - Case Studies in Chemical and Environmental Engineering

M1 - 100739

ER -

Crafting the future: Enhancing gas separation with nanoarchitectonics of bimetallic Ni–Co-ZIF-67 in polysulfone-based mixed matrix membranes

Abstract

Keywords

UN SDGs

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