Electrochemical decolorization of dye wastewater by surface-activated boron-doped nanocrystalline diamond electrode

Chienhung Chen, Ervin Nurhayati, Yaju Juang*, Chihpin Huang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)


Complex organics contained in dye wastewater are difficult to degrade and often require electrochemical advanced oxidation processes (EAOPs) to treat it. Surface activation of the electrode used in such treatment is an important factor determining the success of the process. The performance of boron-doped nanocrystalline diamond (BD-NCD) film electrode for decolorization of Acid Yellow (AY-36) azo dye with respect to the surface activation by electrochemical polarization was studied. Anodic polarization found to be more suitable as electrode pretreatment compared to cathodic one. After anodic polarization, the originally H-terminated surface of BD-NCD was changed into O-terminated, making it more hydrophilic. Due to the oxidation of surface functional groups and some portion of sp2 carbon in the BD-NCD film during anodic polarization, the electrode was successfully being activated showing lower background current, wider potential window and considerably less surface activity compared to the non-polarized one. Consequently, electrooxidation (EO) capability of the anodically-polarized BD-NCD to degrade AY-36 dye was significantly enhanced, capable of nearly total decolorization and chemical oxygen demand (COD) removal even after several times of re-using. The BD-NCD film electrode favored acidic condition for the dye degradation; and the presence of chloride ion in the solution was found to be more advantageous than sulfate active species.

Original languageEnglish
Pages (from-to)100-107
Number of pages8
JournalJournal of Environmental Sciences (China)
Publication statusPublished - 7 Sept 2015
Externally publishedYes


  • Acid Yellow (AY-36)
  • Azo dye
  • Boron-doped NCD
  • Electrochemical polarization
  • Electrooxidation
  • Surface activation


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