Electrochemical performance of Fe3O4 micro flower as anode for lithium ion batteries

Lukman Noerochim; Dika Anggara; Diah Susanti; Achmad Subhan; Sudaryanto

doi:10.1063/1.5030279

Electrochemical performance of Fe₃O₄ micro flower as anode for lithium ion batteries

Lukman Noerochim^*, Dika Anggara, Diah Susanti, Achmad Subhan, Sudaryanto

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

Graphite is generally employed in commercial lithium ion batteries which has a specific capacity of 372 mAh/g. In this study, graphite is replaced with carbon-coated magnetite (Fe₃O₄/C) which has large theoretical specific capacity of 926 mAh/g, environmental friendly, and low cost production. The synthesis of Fe₃O₄/C is carried out by hydrothermal method with reacting FeCl₃ and hexamethylenetetramine (HMT) at temperature variation of 160, 170 and 180°C. The following process is heated by calcination at temperature variations 450, 500 and 550°C. XRD and SEM results show that the as-prepared Fe₃O₄/C powder has a single phase of Fe₃O₄ and morphology micro-flowers like with size between 700 nm - 3 μm. CV test results show redox reaction occurs in the voltage range between 0.21-0.85 V and 1.68-1.81 V. The highest specific discharge capacity is obtained 644 mAh/g for specimen with temperature hydrothermal of 170°C and temperature calcination of 550°C. This result shows that Fe₃O₄/C has a high potential as anode material for lithium ion battery.

Original language	English
Title of host publication	Proceedings of the 3rd International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2017
Subtitle of host publication	Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future
Editors	Mas Irfan P. Hidayat
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735416406
DOIs	https://doi.org/10.1063/1.5030279
Publication status	Published - 3 Apr 2018
Event	3rd International Conference on Materials and Metallurgical Engineering and Technology: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future, ICOMMET 2017 - Surabaya, Indonesia Duration: 30 Oct 2017 → 31 Oct 2017

Publication series

Name	AIP Conference Proceedings
Volume	1945
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	3rd International Conference on Materials and Metallurgical Engineering and Technology: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future, ICOMMET 2017
Country/Territory	Indonesia
City	Surabaya
Period	30/10/17 → 31/10/17

Keywords

Anode
FeO
carbon
hydrothermal
lithium ion batteries

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1063/1.5030279

Cite this

Noerochim, L., Anggara, D., Susanti, D., Subhan, A., & Sudaryanto (2018). Electrochemical performance of Fe₃O₄ micro flower as anode for lithium ion batteries. In M. I. P. Hidayat (Ed.), Proceedings of the 3rd International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2017: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future Article 020057 (AIP Conference Proceedings; Vol. 1945). American Institute of Physics Inc.. https://doi.org/10.1063/1.5030279

Noerochim, Lukman ; Anggara, Dika ; Susanti, Diah et al. / Electrochemical performance of Fe₃O₄ micro flower as anode for lithium ion batteries. Proceedings of the 3rd International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2017: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future. editor / Mas Irfan P. Hidayat. American Institute of Physics Inc., 2018. (AIP Conference Proceedings).

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abstract = "Graphite is generally employed in commercial lithium ion batteries which has a specific capacity of 372 mAh/g. In this study, graphite is replaced with carbon-coated magnetite (Fe3O4/C) which has large theoretical specific capacity of 926 mAh/g, environmental friendly, and low cost production. The synthesis of Fe3O4/C is carried out by hydrothermal method with reacting FeCl3 and hexamethylenetetramine (HMT) at temperature variation of 160, 170 and 180°C. The following process is heated by calcination at temperature variations 450, 500 and 550°C. XRD and SEM results show that the as-prepared Fe3O4/C powder has a single phase of Fe3O4 and morphology micro-flowers like with size between 700 nm - 3 μm. CV test results show redox reaction occurs in the voltage range between 0.21-0.85 V and 1.68-1.81 V. The highest specific discharge capacity is obtained 644 mAh/g for specimen with temperature hydrothermal of 170°C and temperature calcination of 550°C. This result shows that Fe3O4/C has a high potential as anode material for lithium ion battery.",

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author = "Lukman Noerochim and Dika Anggara and Diah Susanti and Achmad Subhan and Sudaryanto",

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Noerochim, L, Anggara, D, Susanti, D, Subhan, A & Sudaryanto 2018, Electrochemical performance of Fe₃O₄ micro flower as anode for lithium ion batteries. in MIP Hidayat (ed.), Proceedings of the 3rd International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2017: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future., 020057, AIP Conference Proceedings, vol. 1945, American Institute of Physics Inc., 3rd International Conference on Materials and Metallurgical Engineering and Technology: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future, ICOMMET 2017, Surabaya, Indonesia, 30/10/17. https://doi.org/10.1063/1.5030279

Electrochemical performance of Fe₃O₄ micro flower as anode for lithium ion batteries. / Noerochim, Lukman; Anggara, Dika; Susanti, Diah et al.
Proceedings of the 3rd International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2017: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future. ed. / Mas Irfan P. Hidayat. American Institute of Physics Inc., 2018. 020057 (AIP Conference Proceedings; Vol. 1945).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Noerochim, Lukman

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AU - Susanti, Diah

AU - Subhan, Achmad

AU - Sudaryanto,

PY - 2018/4/3

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N2 - Graphite is generally employed in commercial lithium ion batteries which has a specific capacity of 372 mAh/g. In this study, graphite is replaced with carbon-coated magnetite (Fe3O4/C) which has large theoretical specific capacity of 926 mAh/g, environmental friendly, and low cost production. The synthesis of Fe3O4/C is carried out by hydrothermal method with reacting FeCl3 and hexamethylenetetramine (HMT) at temperature variation of 160, 170 and 180°C. The following process is heated by calcination at temperature variations 450, 500 and 550°C. XRD and SEM results show that the as-prepared Fe3O4/C powder has a single phase of Fe3O4 and morphology micro-flowers like with size between 700 nm - 3 μm. CV test results show redox reaction occurs in the voltage range between 0.21-0.85 V and 1.68-1.81 V. The highest specific discharge capacity is obtained 644 mAh/g for specimen with temperature hydrothermal of 170°C and temperature calcination of 550°C. This result shows that Fe3O4/C has a high potential as anode material for lithium ion battery.

AB - Graphite is generally employed in commercial lithium ion batteries which has a specific capacity of 372 mAh/g. In this study, graphite is replaced with carbon-coated magnetite (Fe3O4/C) which has large theoretical specific capacity of 926 mAh/g, environmental friendly, and low cost production. The synthesis of Fe3O4/C is carried out by hydrothermal method with reacting FeCl3 and hexamethylenetetramine (HMT) at temperature variation of 160, 170 and 180°C. The following process is heated by calcination at temperature variations 450, 500 and 550°C. XRD and SEM results show that the as-prepared Fe3O4/C powder has a single phase of Fe3O4 and morphology micro-flowers like with size between 700 nm - 3 μm. CV test results show redox reaction occurs in the voltage range between 0.21-0.85 V and 1.68-1.81 V. The highest specific discharge capacity is obtained 644 mAh/g for specimen with temperature hydrothermal of 170°C and temperature calcination of 550°C. This result shows that Fe3O4/C has a high potential as anode material for lithium ion battery.

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Noerochim L, Anggara D, Susanti D, Subhan A, Sudaryanto. Electrochemical performance of Fe₃O₄ micro flower as anode for lithium ion batteries. In Hidayat MIP, editor, Proceedings of the 3rd International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2017: Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future. American Institute of Physics Inc. 2018. 020057. (AIP Conference Proceedings). doi: 10.1063/1.5030279