Electrochemical synthesis of polymelamine/gold nanoparticle modified carbon paste electrode as voltammetric sensor of dopamine

Muji HARSINI; Bernadeta Ayu WIDYANINGRUM; Erna FITRIANY; Denok Risky AYUPARAMITA; Ainiy Nur FARIDA; Afaf FARIDA; Fredy KURNIAWAN; Satya Candra WIBAWASAKTI

doi:10.1016/j.cjac.2022.100052

Electrochemical synthesis of polymelamine/gold nanoparticle modified carbon paste electrode as voltammetric sensor of dopamine

Muji HARSINI^*, Bernadeta Ayu WIDYANINGRUM, Erna FITRIANY, Denok Risky AYUPARAMITA, Ainiy Nur FARIDA, Afaf FARIDA, Fredy KURNIAWAN, Satya Candra WIBAWASAKTI

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Modifications of carbon paste electrodes (CPE) with polymelamine (PM) and gold nanoparticles (AuNPs) as dopamine (DA) sensors have been investigated. Electrodes were made by coating PM by electropolymerization from melamine solution on the surface of CPE, then AuNPs were made by electrochemically reducing HAuCl₄ solution. AuNPs/PM/CPE electrodes were used as dopamine sensors by using cyclic voltammetry (CV) and pulse differential voltammetry (DPV) techniques. The results showed that the electrodes gave a linearity of 0.2–11 µM, a detection limit of 0.067 µM, and recovery value of 98.78 %± 0.34% in the analysis of urine samples spiked with dopamine. The electrodes gave perfect peak potential for separation from DA, uric acid (UA) and ascorbic acid (AA).

Original language	English
Article number	100052
Journal	Chinese Journal of Analytical Chemistry
Volume	50
Issue number	4
DOIs	https://doi.org/10.1016/j.cjac.2022.100052
Publication status	Published - Apr 2022

Keywords

Dopamine
Electropolymerization
Gold nanoparticles
Modified electrode
Polymelamine
Voltammetry

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10.1016/j.cjac.2022.100052

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HARSINI, M., WIDYANINGRUM, B. A., FITRIANY, E., AYUPARAMITA, D. R., FARIDA, A. N., FARIDA, A., KURNIAWAN, F., & WIBAWASAKTI, S. C. (2022). Electrochemical synthesis of polymelamine/gold nanoparticle modified carbon paste electrode as voltammetric sensor of dopamine. Chinese Journal of Analytical Chemistry, 50(4), Article 100052. https://doi.org/10.1016/j.cjac.2022.100052

@article{385f6f1835844c52b7a8ac240fd23413,

title = "Electrochemical synthesis of polymelamine/gold nanoparticle modified carbon paste electrode as voltammetric sensor of dopamine",

abstract = "Modifications of carbon paste electrodes (CPE) with polymelamine (PM) and gold nanoparticles (AuNPs) as dopamine (DA) sensors have been investigated. Electrodes were made by coating PM by electropolymerization from melamine solution on the surface of CPE, then AuNPs were made by electrochemically reducing HAuCl4 solution. AuNPs/PM/CPE electrodes were used as dopamine sensors by using cyclic voltammetry (CV) and pulse differential voltammetry (DPV) techniques. The results showed that the electrodes gave a linearity of 0.2–11 µM, a detection limit of 0.067 µM, and recovery value of 98.78 %± 0.34% in the analysis of urine samples spiked with dopamine. The electrodes gave perfect peak potential for separation from DA, uric acid (UA) and ascorbic acid (AA).",

keywords = "Dopamine, Electropolymerization, Gold nanoparticles, Modified electrode, Polymelamine, Voltammetry",

author = "Muji HARSINI and WIDYANINGRUM, {Bernadeta Ayu} and Erna FITRIANY and AYUPARAMITA, {Denok Risky} and FARIDA, {Ainiy Nur} and Afaf FARIDA and Fredy KURNIAWAN and WIBAWASAKTI, {Satya Candra}",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2022",

month = apr,

doi = "10.1016/j.cjac.2022.100052",

language = "English",

volume = "50",

journal = "Chinese Journal of Analytical Chemistry",

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TY - JOUR

T1 - Electrochemical synthesis of polymelamine/gold nanoparticle modified carbon paste electrode as voltammetric sensor of dopamine

AU - HARSINI, Muji

AU - WIDYANINGRUM, Bernadeta Ayu

AU - FITRIANY, Erna

AU - AYUPARAMITA, Denok Risky

AU - FARIDA, Ainiy Nur

AU - FARIDA, Afaf

AU - KURNIAWAN, Fredy

AU - WIBAWASAKTI, Satya Candra

PY - 2022/4

Y1 - 2022/4

N2 - Modifications of carbon paste electrodes (CPE) with polymelamine (PM) and gold nanoparticles (AuNPs) as dopamine (DA) sensors have been investigated. Electrodes were made by coating PM by electropolymerization from melamine solution on the surface of CPE, then AuNPs were made by electrochemically reducing HAuCl4 solution. AuNPs/PM/CPE electrodes were used as dopamine sensors by using cyclic voltammetry (CV) and pulse differential voltammetry (DPV) techniques. The results showed that the electrodes gave a linearity of 0.2–11 µM, a detection limit of 0.067 µM, and recovery value of 98.78 %± 0.34% in the analysis of urine samples spiked with dopamine. The electrodes gave perfect peak potential for separation from DA, uric acid (UA) and ascorbic acid (AA).

AB - Modifications of carbon paste electrodes (CPE) with polymelamine (PM) and gold nanoparticles (AuNPs) as dopamine (DA) sensors have been investigated. Electrodes were made by coating PM by electropolymerization from melamine solution on the surface of CPE, then AuNPs were made by electrochemically reducing HAuCl4 solution. AuNPs/PM/CPE electrodes were used as dopamine sensors by using cyclic voltammetry (CV) and pulse differential voltammetry (DPV) techniques. The results showed that the electrodes gave a linearity of 0.2–11 µM, a detection limit of 0.067 µM, and recovery value of 98.78 %± 0.34% in the analysis of urine samples spiked with dopamine. The electrodes gave perfect peak potential for separation from DA, uric acid (UA) and ascorbic acid (AA).

KW - Dopamine

KW - Electropolymerization

KW - Gold nanoparticles

KW - Modified electrode

KW - Polymelamine

KW - Voltammetry

UR - http://www.scopus.com/inward/record.url?scp=85126295155&partnerID=8YFLogxK

U2 - 10.1016/j.cjac.2022.100052

DO - 10.1016/j.cjac.2022.100052

M3 - Article

AN - SCOPUS:85126295155

SN - 0253-3820

VL - 50

JO - Chinese Journal of Analytical Chemistry

JF - Chinese Journal of Analytical Chemistry

IS - 4

M1 - 100052

ER -

Electrochemical synthesis of polymelamine/gold nanoparticle modified carbon paste electrode as voltammetric sensor of dopamine

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