TY - GEN
T1 - Examination of natural and standard fe3o4 powders using x-ray absorption near-edge spectroscopy (Xanes)
AU - Budi, Hariyanto
AU - Husain, Husain
AU - Supanun, Lapboonruang
AU - Suminar, Pratapa
N1 - Publisher Copyright:
© 2019 Trans Tech Publications Ltd, Switzerland.
PY - 2019
Y1 - 2019
N2 - Investigation of Fe K-edge X-Ray Absorption Near Edge Spectroscopy (XANES) spectra of Fe3O4 (FeO.Fe2O3) from natural source compared with the Fe3O4 standard is presented. The natural Fe3O4 powder was prepared from ironstone of Tanah Laut, Kalimantan Selatan by co-precipitation method. XANES measurements in transmission mode were performed at the Synchrotron Light Research Institute (SLRI), Nakhon Ratchasima, Thailand. XRD phase analysis confirms that the synthesized Fe3O4 powder is a single phase, but it cannot determine the proportion of Fe2O3 and FeO in the structure. TEM measurement confirms that the particle size of natural Fe3O4 about 10 nm. Qualitative analysis of the pre-edge XANES data revealed that the absorbing atom in the XAS measurement is Fe3+. Meanwhile, the absorption edge (E0) values of natural and standard Fe3O4 powders were 7126.44 eV and 7125.02 eV, respectively. The proportion was then acquired using XANES data analysis through Linear Combination Fitting (LCF). It was found that the natural Fe3O4 sample consisted of 98 wt. % Fe2O3 and 2 wt.% FeO, while the standard Fe3O4 powder consisted of 96 wt. % Fe2O3 and 4 wt. % FeO. The mechanism of the absorption in both samples is also described and compared.
AB - Investigation of Fe K-edge X-Ray Absorption Near Edge Spectroscopy (XANES) spectra of Fe3O4 (FeO.Fe2O3) from natural source compared with the Fe3O4 standard is presented. The natural Fe3O4 powder was prepared from ironstone of Tanah Laut, Kalimantan Selatan by co-precipitation method. XANES measurements in transmission mode were performed at the Synchrotron Light Research Institute (SLRI), Nakhon Ratchasima, Thailand. XRD phase analysis confirms that the synthesized Fe3O4 powder is a single phase, but it cannot determine the proportion of Fe2O3 and FeO in the structure. TEM measurement confirms that the particle size of natural Fe3O4 about 10 nm. Qualitative analysis of the pre-edge XANES data revealed that the absorbing atom in the XAS measurement is Fe3+. Meanwhile, the absorption edge (E0) values of natural and standard Fe3O4 powders were 7126.44 eV and 7125.02 eV, respectively. The proportion was then acquired using XANES data analysis through Linear Combination Fitting (LCF). It was found that the natural Fe3O4 sample consisted of 98 wt. % Fe2O3 and 2 wt.% FeO, while the standard Fe3O4 powder consisted of 96 wt. % Fe2O3 and 4 wt. % FeO. The mechanism of the absorption in both samples is also described and compared.
KW - Absorption mechanism
KW - FeO Standard
KW - FeO powder
KW - XANES
UR - http://www.scopus.com/inward/record.url?scp=85071915066&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/MSF.964.40
DO - 10.4028/www.scientific.net/MSF.964.40
M3 - Conference contribution
AN - SCOPUS:85071915066
SN - 9783035714340
T3 - Materials Science Forum
SP - 40
EP - 44
BT - Seminar on Materials Science and Technology
A2 - Noerochim, Lukman
PB - Trans Tech Publications Ltd
T2 - 4th International Seminar on Science and Technology, ISST 2018
Y2 - 9 August 2018 through 9 August 2018
ER -