Increase of solid polymer electrolyte ionic conductivity using nano-sio2 synthesized from sugarcane bagasse as filler

Yatim Lailun Ni’Mah; Zakkiyyah Hidayatul Muhaiminah; Suprapto Suprapto

doi:10.3390/polym13234240

Increase of solid polymer electrolyte ionic conductivity using nano-sio₂ synthesized from sugarcane bagasse as filler

Yatim Lailun Ni’Mah^*, Zakkiyyah Hidayatul Muhaiminah, Suprapto Suprapto

^*Corresponding author for this work

Institut Teknologi Sepuluh Nopember

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The synthesize of solid polymer electrolyte (SPE) based on polyethylene oxide (PEO), NaClO₄ and nano-SiO₂ was carried out by solution cast technique. Nano-SiO₂ was synthesized from sugarcane bagasse using sol-gel method. FTIR analysis was carried out to investigate the bonding between nano-SiO₂ and PEO/NaClO₄ . The morphology of the SPE was characterized using SEM. XRD and DSC analysis showed that SPE crystallinity decreased as nano-SiO₂ concentration was increased. Mechanical analyses were conducted to characterize the SPE tensile strength and elongation at break. EIS analysis was conducted to measure SPE ionic conductivity. The PEO/NaClO₄ SPE with the addition of 5% nano-SiO₂ from sugarcane bagasse at 60^◦C produced SPE with the highest ionic conductivity, 1.18 × 10⁻⁶ S/cm. It was concluded that the addition of nano-SiO₂ increased ionic conductivity and interface stability at the solid polymer electrolyte-PEO/NaClO₄ .

Original language	English
Article number	4240
Journal	Polymers
Volume	13
Issue number	23
DOIs	https://doi.org/10.3390/polym13234240
Publication status	Published - 1 Dec 2021

Keywords

NaClO
Nano-SiO
PEO
Sodium ion
Solid polymer electrolyte

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title = "Increase of solid polymer electrolyte ionic conductivity using nano-sio2 synthesized from sugarcane bagasse as filler",

abstract = "The synthesize of solid polymer electrolyte (SPE) based on polyethylene oxide (PEO), NaClO4 and nano-SiO2 was carried out by solution cast technique. Nano-SiO2 was synthesized from sugarcane bagasse using sol-gel method. FTIR analysis was carried out to investigate the bonding between nano-SiO2 and PEO/NaClO4 . The morphology of the SPE was characterized using SEM. XRD and DSC analysis showed that SPE crystallinity decreased as nano-SiO2 concentration was increased. Mechanical analyses were conducted to characterize the SPE tensile strength and elongation at break. EIS analysis was conducted to measure SPE ionic conductivity. The PEO/NaClO4 SPE with the addition of 5% nano-SiO2 from sugarcane bagasse at 60◦C produced SPE with the highest ionic conductivity, 1.18 × 10−6 S/cm. It was concluded that the addition of nano-SiO2 increased ionic conductivity and interface stability at the solid polymer electrolyte-PEO/NaClO4 .",

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author = "Ni{\textquoteright}Mah, {Yatim Lailun} and Muhaiminah, {Zakkiyyah Hidayatul} and Suprapto Suprapto",

note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

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doi = "10.3390/polym13234240",

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AU - Ni’Mah, Yatim Lailun

AU - Muhaiminah, Zakkiyyah Hidayatul

AU - Suprapto, Suprapto

PY - 2021/12/1

Y1 - 2021/12/1

N2 - The synthesize of solid polymer electrolyte (SPE) based on polyethylene oxide (PEO), NaClO4 and nano-SiO2 was carried out by solution cast technique. Nano-SiO2 was synthesized from sugarcane bagasse using sol-gel method. FTIR analysis was carried out to investigate the bonding between nano-SiO2 and PEO/NaClO4 . The morphology of the SPE was characterized using SEM. XRD and DSC analysis showed that SPE crystallinity decreased as nano-SiO2 concentration was increased. Mechanical analyses were conducted to characterize the SPE tensile strength and elongation at break. EIS analysis was conducted to measure SPE ionic conductivity. The PEO/NaClO4 SPE with the addition of 5% nano-SiO2 from sugarcane bagasse at 60◦C produced SPE with the highest ionic conductivity, 1.18 × 10−6 S/cm. It was concluded that the addition of nano-SiO2 increased ionic conductivity and interface stability at the solid polymer electrolyte-PEO/NaClO4 .

AB - The synthesize of solid polymer electrolyte (SPE) based on polyethylene oxide (PEO), NaClO4 and nano-SiO2 was carried out by solution cast technique. Nano-SiO2 was synthesized from sugarcane bagasse using sol-gel method. FTIR analysis was carried out to investigate the bonding between nano-SiO2 and PEO/NaClO4 . The morphology of the SPE was characterized using SEM. XRD and DSC analysis showed that SPE crystallinity decreased as nano-SiO2 concentration was increased. Mechanical analyses were conducted to characterize the SPE tensile strength and elongation at break. EIS analysis was conducted to measure SPE ionic conductivity. The PEO/NaClO4 SPE with the addition of 5% nano-SiO2 from sugarcane bagasse at 60◦C produced SPE with the highest ionic conductivity, 1.18 × 10−6 S/cm. It was concluded that the addition of nano-SiO2 increased ionic conductivity and interface stability at the solid polymer electrolyte-PEO/NaClO4 .

KW - NaClO

KW - Nano-SiO

KW - PEO

KW - Sodium ion

KW - Solid polymer electrolyte

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DO - 10.3390/polym13234240

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SN - 2073-4360

VL - 13

JO - Polymers

JF - Polymers

IS - 23

M1 - 4240

ER -

Increase of solid polymer electrolyte ionic conductivity using nano-sio₂ synthesized from sugarcane bagasse as filler

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Keywords

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