Metal (boro-) hydrides for high energy density storage and relevant emerging technologies

L. J. Bannenberg; M. Heere; H. Benzidi; J. Montero; E. M. Dematteis; S. Suwarno; T. Jaroń; M. Winny; P. A. Orłowski; W. Wegner; A. Starobrat; K. J. Fijałkowski; W. Grochala; Z. Qian; J. P. Bonnet; I. Nuta; W. Lohstroh; C. Zlotea; O. Mounkachi; F. Cuevas; C. Chatillon; M. Latroche; M. Fichtner; M. Baricco; B. C. Hauback; A. El Kharbachi

doi:10.1016/j.ijhydene.2020.08.119

Metal (boro-) hydrides for high energy density storage and relevant emerging technologies

L. J. Bannenberg
, M. Heere
, H. Benzidi
, J. Montero
, E. M. Dematteis
, S. Suwarno
, T. Jaroń^*
, M. Winny
, P. A. Orłowski
, W. Wegner
, A. Starobrat
, K. J. Fijałkowski
, W. Grochala
, Z. Qian
, J. P. Bonnet
, I. Nuta
, W. Lohstroh
, C. Zlotea
, O. Mounkachi
, F. Cuevas

C. Chatillon, M. Latroche, M. Fichtner, M. Baricco, B. C. Hauback, A. El Kharbachi^*

^*Corresponding author for this work

Laboratory of Metallurgy

Delft University of Technology
Karlsruhe Institute of Technology
Technical University of Munich
Mohammed V University in Rabat
Université Paris-Est Créteil
University of Turin
University of Warsaw
Shandong University
Université de Picardie Jules Verne
Université Grenoble Alpes
Institute for Energy Technology

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

The current energy transition imposes a rapid implementation of energy storage systems with high energy density and eminent regeneration and cycling efficiency. Metal hydrides are potential candidates for generalized energy storage, when coupled with fuel cell units and/or batteries. An overview of ongoing research is reported and discussed in this review work on the light of application as hydrogen and heat storage matrices, as well as thin films for hydrogen optical sensors. These include a selection of single-metal hydrides, Ti–V(Fe) based intermetallics, multi-principal element alloys (high-entropy alloys), and a series of novel synthetically accessible metal borohydrides. Metal hydride materials can be as well of important usefulness for MH-based electrodes with high capacity (e.g. MgH₂ ~ 2000 mA h g⁻¹) and solid-state electrolytes displaying high ionic conductivity suitable, respectively, for Li-ion and Li/Mg battery technologies. To boost further research and development directions some characterization techniques dedicated to the study of M-H interactions, their equilibrium reactions, and additional quantification of hydrogen concentration in thin film and bulk hydrides are briefly discussed.

Original language	English
Pages (from-to)	33687-33730
Number of pages	44
Journal	International Journal of Hydrogen Energy
Volume	45
Issue number	58
DOIs	https://doi.org/10.1016/j.ijhydene.2020.08.119
Publication status	Published - 27 Nov 2020

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Electrochemical energy storage
Hydrogen sensors
Hydrogen storage
Metal borohydrides
Metal hydrides

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10.1016/j.ijhydene.2020.08.119

Cite this

Bannenberg, L. J., Heere, M., Benzidi, H., Montero, J., Dematteis, E. M., Suwarno, S., Jaroń, T., Winny, M., Orłowski, P. A., Wegner, W., Starobrat, A., Fijałkowski, K. J., Grochala, W., Qian, Z., Bonnet, J. P., Nuta, I., Lohstroh, W., Zlotea, C., Mounkachi, O., ... El Kharbachi, A. (2020). Metal (boro-) hydrides for high energy density storage and relevant emerging technologies. International Journal of Hydrogen Energy, 45(58), 33687-33730. https://doi.org/10.1016/j.ijhydene.2020.08.119

@article{b1a2f550b2094393b1bf03d89c4ee220,

title = "Metal (boro-) hydrides for high energy density storage and relevant emerging technologies",

abstract = "The current energy transition imposes a rapid implementation of energy storage systems with high energy density and eminent regeneration and cycling efficiency. Metal hydrides are potential candidates for generalized energy storage, when coupled with fuel cell units and/or batteries. An overview of ongoing research is reported and discussed in this review work on the light of application as hydrogen and heat storage matrices, as well as thin films for hydrogen optical sensors. These include a selection of single-metal hydrides, Ti–V(Fe) based intermetallics, multi-principal element alloys (high-entropy alloys), and a series of novel synthetically accessible metal borohydrides. Metal hydride materials can be as well of important usefulness for MH-based electrodes with high capacity (e.g. MgH2 \textasciitilde{} 2000 mA h g−1) and solid-state electrolytes displaying high ionic conductivity suitable, respectively, for Li-ion and Li/Mg battery technologies. To boost further research and development directions some characterization techniques dedicated to the study of M-H interactions, their equilibrium reactions, and additional quantification of hydrogen concentration in thin film and bulk hydrides are briefly discussed.",

keywords = "Electrochemical energy storage, Hydrogen sensors, Hydrogen storage, Metal borohydrides, Metal hydrides",

author = "Bannenberg, \{L. J.\} and M. Heere and H. Benzidi and J. Montero and Dematteis, \{E. M.\} and S. Suwarno and T. Jaro{\'n} and M. Winny and Or{\l}owski, \{P. A.\} and W. Wegner and A. Starobrat and Fija{\l}kowski, \{K. J.\} and W. Grochala and Z. Qian and Bonnet, \{J. P.\} and I. Nuta and W. Lohstroh and C. Zlotea and O. Mounkachi and F. Cuevas and C. Chatillon and M. Latroche and M. Fichtner and M. Baricco and Hauback, \{B. C.\} and \{El Kharbachi\}, A.",

note = "Publisher Copyright: {\textcopyright} 2020 Hydrogen Energy Publications LLC",

year = "2020",

month = nov,

day = "27",

doi = "10.1016/j.ijhydene.2020.08.119",

language = "English",

volume = "45",

pages = "33687--33730",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

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Bannenberg, LJ, Heere, M, Benzidi, H, Montero, J, Dematteis, EM, Suwarno, S, Jaroń, T, Winny, M, Orłowski, PA, Wegner, W, Starobrat, A, Fijałkowski, KJ, Grochala, W, Qian, Z, Bonnet, JP, Nuta, I, Lohstroh, W, Zlotea, C, Mounkachi, O, Cuevas, F, Chatillon, C, Latroche, M, Fichtner, M, Baricco, M, Hauback, BC & El Kharbachi, A 2020, 'Metal (boro-) hydrides for high energy density storage and relevant emerging technologies', International Journal of Hydrogen Energy, vol. 45, no. 58, pp. 33687-33730. https://doi.org/10.1016/j.ijhydene.2020.08.119

TY - JOUR

T1 - Metal (boro-) hydrides for high energy density storage and relevant emerging technologies

AU - Bannenberg, L. J.

AU - Heere, M.

AU - Benzidi, H.

AU - Montero, J.

AU - Dematteis, E. M.

AU - Suwarno, S.

AU - Jaroń, T.

AU - Winny, M.

AU - Orłowski, P. A.

AU - Wegner, W.

AU - Starobrat, A.

AU - Fijałkowski, K. J.

AU - Grochala, W.

AU - Qian, Z.

AU - Bonnet, J. P.

AU - Nuta, I.

AU - Lohstroh, W.

AU - Zlotea, C.

AU - Mounkachi, O.

AU - Cuevas, F.

AU - Chatillon, C.

AU - Latroche, M.

AU - Fichtner, M.

AU - Baricco, M.

AU - Hauback, B. C.

AU - El Kharbachi, A.

PY - 2020/11/27

Y1 - 2020/11/27

N2 - The current energy transition imposes a rapid implementation of energy storage systems with high energy density and eminent regeneration and cycling efficiency. Metal hydrides are potential candidates for generalized energy storage, when coupled with fuel cell units and/or batteries. An overview of ongoing research is reported and discussed in this review work on the light of application as hydrogen and heat storage matrices, as well as thin films for hydrogen optical sensors. These include a selection of single-metal hydrides, Ti–V(Fe) based intermetallics, multi-principal element alloys (high-entropy alloys), and a series of novel synthetically accessible metal borohydrides. Metal hydride materials can be as well of important usefulness for MH-based electrodes with high capacity (e.g. MgH2 ~ 2000 mA h g−1) and solid-state electrolytes displaying high ionic conductivity suitable, respectively, for Li-ion and Li/Mg battery technologies. To boost further research and development directions some characterization techniques dedicated to the study of M-H interactions, their equilibrium reactions, and additional quantification of hydrogen concentration in thin film and bulk hydrides are briefly discussed.

AB - The current energy transition imposes a rapid implementation of energy storage systems with high energy density and eminent regeneration and cycling efficiency. Metal hydrides are potential candidates for generalized energy storage, when coupled with fuel cell units and/or batteries. An overview of ongoing research is reported and discussed in this review work on the light of application as hydrogen and heat storage matrices, as well as thin films for hydrogen optical sensors. These include a selection of single-metal hydrides, Ti–V(Fe) based intermetallics, multi-principal element alloys (high-entropy alloys), and a series of novel synthetically accessible metal borohydrides. Metal hydride materials can be as well of important usefulness for MH-based electrodes with high capacity (e.g. MgH2 ~ 2000 mA h g−1) and solid-state electrolytes displaying high ionic conductivity suitable, respectively, for Li-ion and Li/Mg battery technologies. To boost further research and development directions some characterization techniques dedicated to the study of M-H interactions, their equilibrium reactions, and additional quantification of hydrogen concentration in thin film and bulk hydrides are briefly discussed.

KW - Electrochemical energy storage

KW - Hydrogen sensors

KW - Hydrogen storage

KW - Metal borohydrides

KW - Metal hydrides

UR - https://www.scopus.com/pages/publications/85090737649

U2 - 10.1016/j.ijhydene.2020.08.119

DO - 10.1016/j.ijhydene.2020.08.119

M3 - Article

AN - SCOPUS:85090737649

SN - 0360-3199

VL - 45

SP - 33687

EP - 33730

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 58

ER -

Metal (boro-) hydrides for high energy density storage and relevant emerging technologies

Abstract

UN SDGs

Keywords

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