TY - JOUR
T1 - Metal-TPP (5,10,15,20-tetraphenylporphyrin) complex compounds as dye sensitizer in dye sensitized solar cells
AU - Darmokoesoemo, Handoko
AU - Murwani, Irmina Kris
AU - Adiarto, Tokok
AU - Prasetyo, Budi
AU - Purwaningsih, Aning
AU - Ati, Andini Laras
AU - Nerpamahisi, Aldila Santi
AU - Ningrum, Evrillia Silvia
AU - Kusuma, Heri Septya
AU - Setyawati, Harsasi
N1 - Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2023/12
Y1 - 2023/12
N2 - The excessive exploitation of fossil fuels requires humans to look for alternative renewable energy sources that are environmentally friendly such as DSSC. DSSC is a solar cell technology that can convert photon energy in sunlight into electrical energy. This research aims to study the performance of complex compounds synthesized from tetraphenylporphyrin (TPP) ligands with metal ions Cr(III), Mn(II) and Fe(III) and applied as dye sensitizers in Dye Sensitized Solar Cell (DSSC). Metal-TPP complexes have been successfully synthesized using the Adler method. The formation of metal-TPP complex compound is indicated by the characterization result using UV–Vis spectrophotometer, FTIR, conductometer test and the observed MLCT phenomenon. In a dye sensitizer application, the performance of the Cr(III)-TPP complex compound shows a short circuit current density value (Jsc) of 8.0 mA/cm2 with an open circuit voltage (Voc) of 0.62 V and an efficiency value (ƞ) of 9.13 %. The Mn(II)-TPP complex compound shows that the short circuit current density value (Jsc) of 8.0 mA/cm2 with an open circuit voltage (Voc) of 0.64 V and an efficiency value (ƞ) of 9.16 %. The Fe(III)-TPP complex compound shows that the short circuit current density value (Jsc) of 8.0 mA/cm2 with an open circuit voltage (Voc) of 0.64 V and an efficiency value (ƞ) of 9.36 %.
AB - The excessive exploitation of fossil fuels requires humans to look for alternative renewable energy sources that are environmentally friendly such as DSSC. DSSC is a solar cell technology that can convert photon energy in sunlight into electrical energy. This research aims to study the performance of complex compounds synthesized from tetraphenylporphyrin (TPP) ligands with metal ions Cr(III), Mn(II) and Fe(III) and applied as dye sensitizers in Dye Sensitized Solar Cell (DSSC). Metal-TPP complexes have been successfully synthesized using the Adler method. The formation of metal-TPP complex compound is indicated by the characterization result using UV–Vis spectrophotometer, FTIR, conductometer test and the observed MLCT phenomenon. In a dye sensitizer application, the performance of the Cr(III)-TPP complex compound shows a short circuit current density value (Jsc) of 8.0 mA/cm2 with an open circuit voltage (Voc) of 0.62 V and an efficiency value (ƞ) of 9.13 %. The Mn(II)-TPP complex compound shows that the short circuit current density value (Jsc) of 8.0 mA/cm2 with an open circuit voltage (Voc) of 0.64 V and an efficiency value (ƞ) of 9.16 %. The Fe(III)-TPP complex compound shows that the short circuit current density value (Jsc) of 8.0 mA/cm2 with an open circuit voltage (Voc) of 0.64 V and an efficiency value (ƞ) of 9.36 %.
KW - Dye-sensitized solar cells
KW - Metal-complex
KW - Photovoltaic
KW - TPP
UR - http://www.scopus.com/inward/record.url?scp=85176128857&partnerID=8YFLogxK
U2 - 10.1016/j.optmat.2023.114527
DO - 10.1016/j.optmat.2023.114527
M3 - Article
AN - SCOPUS:85176128857
SN - 0925-3467
VL - 146
JO - Optical Materials
JF - Optical Materials
M1 - 114527
ER -
