Methanal extrusion in ipso-substitution reactions of hydroxymethylindoles

Jeremy C. Dobrowolski; Kittiya Somphol; Mardi Santoso; Hung Duong; Christopher R. Gardner; Naresh Kumar; David St C. Black

doi:10.1071/CH17257

Methanal extrusion in ipso-substitution reactions of hydroxymethylindoles

Jeremy C. Dobrowolski, Kittiya Somphol, Mardi Santoso, Hung Duong, Christopher R. Gardner, Naresh Kumar, David St C. Black^*

^*Corresponding author for this work

University of New South Wales

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A range of 3-hydroxymethylindoles undergo acid-catalysed reactions involving ipso-electrophilic substitution with the extrusion of methanal and the formation of diindolylmethane moieties. Both inter-and intramolecular processes lead to macrocyclic compounds 10 and 14.

Original language	English
Pages (from-to)	1188-1195
Number of pages	8
Journal	Australian Journal of Chemistry
Volume	70
Issue number	11
DOIs	https://doi.org/10.1071/CH17257
Publication status	Published - 2017
Externally published	Yes

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title = "Methanal extrusion in ipso-substitution reactions of hydroxymethylindoles",

abstract = "A range of 3-hydroxymethylindoles undergo acid-catalysed reactions involving ipso-electrophilic substitution with the extrusion of methanal and the formation of diindolylmethane moieties. Both inter-and intramolecular processes lead to macrocyclic compounds 10 and 14.",

author = "Dobrowolski, {Jeremy C.} and Kittiya Somphol and Mardi Santoso and Hung Duong and Gardner, {Christopher R.} and Naresh Kumar and Black, {David St C.}",

note = "Publisher Copyright: {\textcopyright} CSIRO 2017.",

year = "2017",

doi = "10.1071/CH17257",

language = "English",

volume = "70",

pages = "1188--1195",

journal = "Australian Journal of Chemistry",

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T1 - Methanal extrusion in ipso-substitution reactions of hydroxymethylindoles

AU - Dobrowolski, Jeremy C.

AU - Somphol, Kittiya

AU - Santoso, Mardi

AU - Duong, Hung

AU - Gardner, Christopher R.

AU - Kumar, Naresh

AU - Black, David St C.

PY - 2017

Y1 - 2017

N2 - A range of 3-hydroxymethylindoles undergo acid-catalysed reactions involving ipso-electrophilic substitution with the extrusion of methanal and the formation of diindolylmethane moieties. Both inter-and intramolecular processes lead to macrocyclic compounds 10 and 14.

AB - A range of 3-hydroxymethylindoles undergo acid-catalysed reactions involving ipso-electrophilic substitution with the extrusion of methanal and the formation of diindolylmethane moieties. Both inter-and intramolecular processes lead to macrocyclic compounds 10 and 14.

UR - http://www.scopus.com/inward/record.url?scp=85032703055&partnerID=8YFLogxK

U2 - 10.1071/CH17257

DO - 10.1071/CH17257

M3 - Article

AN - SCOPUS:85032703055

SN - 0004-9425

VL - 70

SP - 1188

EP - 1195

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 11

ER -

Methanal extrusion in ipso-substitution reactions of hydroxymethylindoles

Abstract

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