TY - JOUR
T1 - Molybdenum-lanthanum supported on nano-HZSM-5 as catalyst for hydroprocessing of Cerbera manghas oil
AU - Muttaqii, Muhammad Al
AU - Annas, Dicky
AU - Yati, Indri
AU - Kurniawan, Hendris Hendarsyah
AU - Ndruru, Sun Theo Constan Lotebulo
AU - Priyanto, Sugeng
AU - Sudibyo,
AU - Aziz, Abdul
AU - Prasetyoko, Didik
AU - Nugraha, Reva Edra
AU - Marlinda, Lenny
N1 - Publisher Copyright:
© 2025 Elsevier B.V.
PY - 2025/3
Y1 - 2025/3
N2 - Non-edible vegetable oils have proven to be promising crude oils for biofuel production. Carbera manghas oil (CMO) is an alternative of non-edible feedstock for biofuel production. The oil from Carbera manghas fruit makes up 46–64 % of the seed's content. The aim of this study was to investigate the effect of Mo-La/NHZ catalyst through a hydroprocessing reaction. The catalysts were characterized by X-ray diffraction (XRD), Brunauer Emmet Teller (BET), and Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX). The liquid product was analyzed by Fourier Transform Infrared Spectroscopic (FTIR) and gas chromatography–mass spectrometry (GC–MS). The experimental condition of hydroprocessing reaction such as varied temperature (250, 300, 350) °C with the reaction pressure at 20–40 bar, metals loading of the catalyst (5 % and 10 %), and the ratio of total metals (1:1 and 1:2). Then, the process of hydroprocessing used 0.5 g of the catalyst and 15 mL of feedstock oil in a batch reactor for 2 h. The results showed that all catalysts were able to convert CMO into biofuel hydrocarbon. The best temperature was obtained for hydroprocessing process to convert CMO into biofuel is 350 °C using Mo-La/NHZ 10 % 1:2 catalyst with a yield for gasoil of 10.61 %, kerosene of 10.48 %, and gasoline of 0.68 %.
AB - Non-edible vegetable oils have proven to be promising crude oils for biofuel production. Carbera manghas oil (CMO) is an alternative of non-edible feedstock for biofuel production. The oil from Carbera manghas fruit makes up 46–64 % of the seed's content. The aim of this study was to investigate the effect of Mo-La/NHZ catalyst through a hydroprocessing reaction. The catalysts were characterized by X-ray diffraction (XRD), Brunauer Emmet Teller (BET), and Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX). The liquid product was analyzed by Fourier Transform Infrared Spectroscopic (FTIR) and gas chromatography–mass spectrometry (GC–MS). The experimental condition of hydroprocessing reaction such as varied temperature (250, 300, 350) °C with the reaction pressure at 20–40 bar, metals loading of the catalyst (5 % and 10 %), and the ratio of total metals (1:1 and 1:2). Then, the process of hydroprocessing used 0.5 g of the catalyst and 15 mL of feedstock oil in a batch reactor for 2 h. The results showed that all catalysts were able to convert CMO into biofuel hydrocarbon. The best temperature was obtained for hydroprocessing process to convert CMO into biofuel is 350 °C using Mo-La/NHZ 10 % 1:2 catalyst with a yield for gasoil of 10.61 %, kerosene of 10.48 %, and gasoline of 0.68 %.
KW - Biofuel
KW - Catalyst
KW - Cerbera manghas oil
KW - Hydroprocessing
UR - http://www.scopus.com/inward/record.url?scp=85214291474&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2024.113855
DO - 10.1016/j.inoche.2024.113855
M3 - Article
AN - SCOPUS:85214291474
SN - 1387-7003
VL - 173
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
M1 - 113855
ER -