Phase study of Mg1-xZnxTiO3powders prepared by dissolved metals mixing method

Musyarofah; Eka F. Damanik; Atut R. Septiana; Dian M. Shoodiqin; Husain; Gatut Yudoyono

doi:10.1063/5.0106315

Phase study of Mg_1-xZn_xTiO₃powders prepared by dissolved metals mixing method

Musyarofah^*, Eka F. Damanik, Atut R. Septiana, Dian M. Shoodiqin, Husain, Gatut Yudoyono

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The effects of calcination temperature and Zn dopant composition on phase composition of Mg1-xZnxTiO3 powders were studied. A simple method of dissolved metals mixing has been accomplished. The metal powders were prepared with a stoichiometric Mg/Zn/Ti in mol% of (1 - x): x:1 for x=0; 0.25; 0.5. The independently dissolved Mg, Zn, and Ti powders in hydrochloric acid solution were mixed and dried then followed by a varied calcination temperature (600, 700, and 800°C) for 4h. A qualitative analysis of X-ray diffraction (XRD) data showed that the calcined powders contained a combination among geikielite, rutile, and periclase. The structural study was revealed by Rietveld analysis of XRD data using Rietica and MAUD software. Geikielite content increased as calcination temperature reaching 94.3%wt for 0 and 0.25 Zn doped samples, otherwise for x=0.5. The roles of calcination temperature and zinc as dopant on geikielite characteristics were also discussed. The increasing calcination temperature and Zn substitution promote the broadening and the shifting position of geikielite peak which indicates a change in the crystallite size and lattice parameters, respectively.

Original language	English
Title of host publication	6th International Symposium on Frontier of Applied Physics, ISFAP 2021
Editors	Mohammad Hamzah Fauzi, Gagus Ketut Sunnardiarto, Mohammad Hasib, Sasfan Arman Wella, Apriadi Salim Adam, M. Jauhar Kholili, Wahyu Dita Saputri, Seramika Ariwahjoedi, Syuhada, Gerald Ensang Timuda, Dwi Hanto, Yuliati Herbani, Witha Berlian Kesuma Putri, Iyon Titok Sugiarto, Deni Shidqi Khaerundini, Ahmad Ridwan T. Nugraha, Edi Suprayoga, Muhandis Shiddiq, Andri Hardiansyah, Salim Mustofa
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735442641
DOIs	https://doi.org/10.1063/5.0106315
Publication status	Published - 14 Nov 2022
Event	6th International Symposium on Frontier of Applied Physics, ISFAP 2021 - South Tangerang, Indonesia Duration: 6 Oct 2021 → 7 Oct 2021

Publication series

Name	AIP Conference Proceedings
Volume	2652
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	6th International Symposium on Frontier of Applied Physics, ISFAP 2021
Country/Territory	Indonesia
City	South Tangerang
Period	6/10/21 → 7/10/21

Keywords

MgTiO3
Rietveld analysis
phase study
structural properties

Access to Document

10.1063/5.0106315

Cite this

Musyarofah, Damanik, E. F., Septiana, A. R., Shoodiqin, D. M., Husain, & Yudoyono, G. (2022). Phase study of Mg_1-xZn_xTiO₃powders prepared by dissolved metals mixing method. In M. H. Fauzi, G. K. Sunnardiarto, M. Hasib, S. A. Wella, A. S. Adam, M. J. Kholili, W. D. Saputri, S. Ariwahjoedi, Syuhada, G. E. Timuda, D. Hanto, Y. Herbani, W. B. K. Putri, I. T. Sugiarto, D. S. Khaerundini, A. R. T. Nugraha, E. Suprayoga, M. Shiddiq, A. Hardiansyah, & S. Mustofa (Eds.), 6th International Symposium on Frontier of Applied Physics, ISFAP 2021 Article 050013 (AIP Conference Proceedings; Vol. 2652). American Institute of Physics Inc.. https://doi.org/10.1063/5.0106315

Musyarofah ; Damanik, Eka F. ; Septiana, Atut R. et al. / Phase study of Mg_1-xZn_xTiO₃powders prepared by dissolved metals mixing method. 6th International Symposium on Frontier of Applied Physics, ISFAP 2021. editor / Mohammad Hamzah Fauzi ; Gagus Ketut Sunnardiarto ; Mohammad Hasib ; Sasfan Arman Wella ; Apriadi Salim Adam ; M. Jauhar Kholili ; Wahyu Dita Saputri ; Seramika Ariwahjoedi ; Syuhada ; Gerald Ensang Timuda ; Dwi Hanto ; Yuliati Herbani ; Witha Berlian Kesuma Putri ; Iyon Titok Sugiarto ; Deni Shidqi Khaerundini ; Ahmad Ridwan T. Nugraha ; Edi Suprayoga ; Muhandis Shiddiq ; Andri Hardiansyah ; Salim Mustofa. American Institute of Physics Inc., 2022. (AIP Conference Proceedings).

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title = "Phase study of Mg1-xZnxTiO3powders prepared by dissolved metals mixing method",

abstract = "The effects of calcination temperature and Zn dopant composition on phase composition of Mg1-xZnxTiO3 powders were studied. A simple method of dissolved metals mixing has been accomplished. The metal powders were prepared with a stoichiometric Mg/Zn/Ti in mol% of (1 - x): x:1 for x=0; 0.25; 0.5. The independently dissolved Mg, Zn, and Ti powders in hydrochloric acid solution were mixed and dried then followed by a varied calcination temperature (600, 700, and 800°C) for 4h. A qualitative analysis of X-ray diffraction (XRD) data showed that the calcined powders contained a combination among geikielite, rutile, and periclase. The structural study was revealed by Rietveld analysis of XRD data using Rietica and MAUD software. Geikielite content increased as calcination temperature reaching 94.3%wt for 0 and 0.25 Zn doped samples, otherwise for x=0.5. The roles of calcination temperature and zinc as dopant on geikielite characteristics were also discussed. The increasing calcination temperature and Zn substitution promote the broadening and the shifting position of geikielite peak which indicates a change in the crystallite size and lattice parameters, respectively.",

keywords = "MgTiO3, Rietveld analysis, phase study, structural properties",

author = "Musyarofah and Damanik, {Eka F.} and Septiana, {Atut R.} and Shoodiqin, {Dian M.} and Husain and Gatut Yudoyono",

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Musyarofah, Damanik, EF, Septiana, AR, Shoodiqin, DM, Husain, & Yudoyono, G 2022, Phase study of Mg_1-xZn_xTiO₃powders prepared by dissolved metals mixing method. in MH Fauzi, GK Sunnardiarto, M Hasib, SA Wella, AS Adam, MJ Kholili, WD Saputri, S Ariwahjoedi, Syuhada, GE Timuda, D Hanto, Y Herbani, WBK Putri, IT Sugiarto, DS Khaerundini, ART Nugraha, E Suprayoga, M Shiddiq, A Hardiansyah & S Mustofa (eds), 6th International Symposium on Frontier of Applied Physics, ISFAP 2021., 050013, AIP Conference Proceedings, vol. 2652, American Institute of Physics Inc., 6th International Symposium on Frontier of Applied Physics, ISFAP 2021, South Tangerang, Indonesia, 6/10/21. https://doi.org/10.1063/5.0106315

Phase study of Mg_1-xZn_xTiO₃powders prepared by dissolved metals mixing method. / Musyarofah; Damanik, Eka F.; Septiana, Atut R. et al.
6th International Symposium on Frontier of Applied Physics, ISFAP 2021. ed. / Mohammad Hamzah Fauzi; Gagus Ketut Sunnardiarto; Mohammad Hasib; Sasfan Arman Wella; Apriadi Salim Adam; M. Jauhar Kholili; Wahyu Dita Saputri; Seramika Ariwahjoedi; Syuhada; Gerald Ensang Timuda; Dwi Hanto; Yuliati Herbani; Witha Berlian Kesuma Putri; Iyon Titok Sugiarto; Deni Shidqi Khaerundini; Ahmad Ridwan T. Nugraha; Edi Suprayoga; Muhandis Shiddiq; Andri Hardiansyah; Salim Mustofa. American Institute of Physics Inc., 2022. 050013 (AIP Conference Proceedings; Vol. 2652).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Phase study of Mg1-xZnxTiO3powders prepared by dissolved metals mixing method

AU - Musyarofah,

AU - Damanik, Eka F.

AU - Septiana, Atut R.

AU - Shoodiqin, Dian M.

AU - Husain,

AU - Yudoyono, Gatut

PY - 2022/11/14

Y1 - 2022/11/14

N2 - The effects of calcination temperature and Zn dopant composition on phase composition of Mg1-xZnxTiO3 powders were studied. A simple method of dissolved metals mixing has been accomplished. The metal powders were prepared with a stoichiometric Mg/Zn/Ti in mol% of (1 - x): x:1 for x=0; 0.25; 0.5. The independently dissolved Mg, Zn, and Ti powders in hydrochloric acid solution were mixed and dried then followed by a varied calcination temperature (600, 700, and 800°C) for 4h. A qualitative analysis of X-ray diffraction (XRD) data showed that the calcined powders contained a combination among geikielite, rutile, and periclase. The structural study was revealed by Rietveld analysis of XRD data using Rietica and MAUD software. Geikielite content increased as calcination temperature reaching 94.3%wt for 0 and 0.25 Zn doped samples, otherwise for x=0.5. The roles of calcination temperature and zinc as dopant on geikielite characteristics were also discussed. The increasing calcination temperature and Zn substitution promote the broadening and the shifting position of geikielite peak which indicates a change in the crystallite size and lattice parameters, respectively.

AB - The effects of calcination temperature and Zn dopant composition on phase composition of Mg1-xZnxTiO3 powders were studied. A simple method of dissolved metals mixing has been accomplished. The metal powders were prepared with a stoichiometric Mg/Zn/Ti in mol% of (1 - x): x:1 for x=0; 0.25; 0.5. The independently dissolved Mg, Zn, and Ti powders in hydrochloric acid solution were mixed and dried then followed by a varied calcination temperature (600, 700, and 800°C) for 4h. A qualitative analysis of X-ray diffraction (XRD) data showed that the calcined powders contained a combination among geikielite, rutile, and periclase. The structural study was revealed by Rietveld analysis of XRD data using Rietica and MAUD software. Geikielite content increased as calcination temperature reaching 94.3%wt for 0 and 0.25 Zn doped samples, otherwise for x=0.5. The roles of calcination temperature and zinc as dopant on geikielite characteristics were also discussed. The increasing calcination temperature and Zn substitution promote the broadening and the shifting position of geikielite peak which indicates a change in the crystallite size and lattice parameters, respectively.

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A2 - Sunnardiarto, Gagus Ketut

A2 - Hasib, Mohammad

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A2 - Adam, Apriadi Salim

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A2 - Saputri, Wahyu Dita

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PB - American Institute of Physics Inc.

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Musyarofah, Damanik EF, Septiana AR, Shoodiqin DM, Husain , Yudoyono G. Phase study of Mg_1-xZn_xTiO₃powders prepared by dissolved metals mixing method. In Fauzi MH, Sunnardiarto GK, Hasib M, Wella SA, Adam AS, Kholili MJ, Saputri WD, Ariwahjoedi S, Syuhada, Timuda GE, Hanto D, Herbani Y, Putri WBK, Sugiarto IT, Khaerundini DS, Nugraha ART, Suprayoga E, Shiddiq M, Hardiansyah A, Mustofa S, editors, 6th International Symposium on Frontier of Applied Physics, ISFAP 2021. American Institute of Physics Inc. 2022. 050013. (AIP Conference Proceedings). doi: 10.1063/5.0106315