TY - GEN
T1 - Porous carbon materials synthesized using IRMOF-3 and furfuryl alcohol as precursor
AU - Deka, Pemta Tia
AU - Ediati, Ratna
N1 - Publisher Copyright:
© 2016 AIP Publishing LLC.
PY - 2016/3/15
Y1 - 2016/3/15
N2 - IRMOF-3 crystals have been synthesized using solvothermal method by adding zinc nitrate hexahydrate with 2-Amino-1,4-benzenedicarboxylic acid in N'N-dimethylformamide (DMF) at 100°C for 24 (note as IR-24) and 72?h (note as IR-72). The obtained crystals were characterized using X-ray Diffraction (XRD), SEM (Scanning Electron Microscopy) and Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX), FTIR and Isothermal adsorption-desorption N2. The diffractogram solids synthesized show characteristic peak at 2θ 6.8, 9.6 and 13.7°. SEM micrograph show cubic shape of IRMOF-3 crystal. Based on FTIR characterization, IRMOF-3 appear at wavelength (1691,46; 1425,3; 1238,21; 1319,22 dan 3504,42)cm-1. The Isotherm of crystal IRMOF-3 at heating time 24?h and 72?h are type IV. The surface area of IR-24 and IR-72 are respectively 24,758?m2/g and 29,139?m2/g with its dominant mesopores. Carbonaceous materials has been successfully synthesized using IR-24, IR-72 and furfuryl alcohol (FA) as second carbon precursor with variation of carbonation temperature 550, 700 and 850°C. The XRD result from both carbonaceous materials show formation of amorphous carbon and caharacteristic peak of ZnO oxide. Micrograph SEM show that carbonaceous materials have cubic shape as IRMOF-3 and SEM-EDX result indicate Zn and nitrogen content of these materials has decrease until temperature 850°C. Porous carbon using IR-24 and FA (notes as C-24) has increased surface area with higher carbonation temperature. The highest surface area is 1495,023 m2/g. Total pore volume and pore size of C-24 from low to high temperature respectively as (0,338; 0,539 and 1,598) cc/g; (0,107; 0,152 and 0,610) cc/g. Porous carbon using IR-72 and FA (notes as C-72) has smaller surface area than C-24 but its also increased during higher carbonation heating. The highest surface area is 1029,668 m2/g.The total pore volume and pore size of these carbon materials from low to high temperature respectively as (0,390; 0,727 and 1,345) cc/g and (0,065; 0,157 and 0,381) cc/g. Carbonaceous materials with high porosity and nitrogen content will be expected increase mechanical properties and hydrogen storage from these materials.
AB - IRMOF-3 crystals have been synthesized using solvothermal method by adding zinc nitrate hexahydrate with 2-Amino-1,4-benzenedicarboxylic acid in N'N-dimethylformamide (DMF) at 100°C for 24 (note as IR-24) and 72?h (note as IR-72). The obtained crystals were characterized using X-ray Diffraction (XRD), SEM (Scanning Electron Microscopy) and Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX), FTIR and Isothermal adsorption-desorption N2. The diffractogram solids synthesized show characteristic peak at 2θ 6.8, 9.6 and 13.7°. SEM micrograph show cubic shape of IRMOF-3 crystal. Based on FTIR characterization, IRMOF-3 appear at wavelength (1691,46; 1425,3; 1238,21; 1319,22 dan 3504,42)cm-1. The Isotherm of crystal IRMOF-3 at heating time 24?h and 72?h are type IV. The surface area of IR-24 and IR-72 are respectively 24,758?m2/g and 29,139?m2/g with its dominant mesopores. Carbonaceous materials has been successfully synthesized using IR-24, IR-72 and furfuryl alcohol (FA) as second carbon precursor with variation of carbonation temperature 550, 700 and 850°C. The XRD result from both carbonaceous materials show formation of amorphous carbon and caharacteristic peak of ZnO oxide. Micrograph SEM show that carbonaceous materials have cubic shape as IRMOF-3 and SEM-EDX result indicate Zn and nitrogen content of these materials has decrease until temperature 850°C. Porous carbon using IR-24 and FA (notes as C-24) has increased surface area with higher carbonation temperature. The highest surface area is 1495,023 m2/g. Total pore volume and pore size of C-24 from low to high temperature respectively as (0,338; 0,539 and 1,598) cc/g; (0,107; 0,152 and 0,610) cc/g. Porous carbon using IR-72 and FA (notes as C-72) has smaller surface area than C-24 but its also increased during higher carbonation heating. The highest surface area is 1029,668 m2/g.The total pore volume and pore size of these carbon materials from low to high temperature respectively as (0,390; 0,727 and 1,345) cc/g and (0,065; 0,157 and 0,381) cc/g. Carbonaceous materials with high porosity and nitrogen content will be expected increase mechanical properties and hydrogen storage from these materials.
KW - IRMOF-3
KW - carbonation temperature.
KW - furfuryl alcohol
KW - porous carbon materials
UR - http://www.scopus.com/inward/record.url?scp=84984537111&partnerID=8YFLogxK
U2 - 10.1063/1.4943346
DO - 10.1063/1.4943346
M3 - Conference contribution
AN - SCOPUS:84984537111
T3 - AIP Conference Proceedings
BT - 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015
A2 - Yasin, Moh.
A2 - Harun, Sulaiman W.
PB - American Institute of Physics Inc.
T2 - 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015
Y2 - 16 October 2015 through 17 October 2015
ER -