Porous Fe2O3 Microspheres as Anode for Lithium-Ion Batteries

L. Noerochim; M. A.T. Indra; H. Purwaningsih; A. Subhan

doi:10.1088/1757-899X/367/1/012038

Porous Fe₂O₃ Microspheres as Anode for Lithium-Ion Batteries

L. Noerochim, M. A.T. Indra, H. Purwaningsih, A. Subhan

Research output: Contribution to journal › Conference article › peer-review

10 Citations (Scopus)

Abstract

In this work, Fe₂O₃ was successfully synthesized by the hydrothermal process at low temperature. FeCl₃.6H₂O as precursor and variation of lysine as hydrolyzing agent were used to preparing Fe₂O₃. SEM images show that the morphology of Fe₂O₃ is porous microsphere with sizes in the range of (1 to 5) μm in diameter. The as-prepared Fe₂O₃ with the 2 M of lysine exhibits excellent cycling performance when used as the anode for lithium ion batteries, obtaining reversible discharge capacity of 172.33 mA•h•g^-1 at 0.5 C after 50 cycles. It is attributed to the unique structure of porous microspheres providing a large surface area which maintains good electronic contact between particles during charge-discharge process. This result demonstrates that Fe₂O₃ porous microsphere has a high potential as anode material for application of lithium-ion battery.

Original language	English
Article number	012038
Journal	IOP Conference Series: Materials Science and Engineering
Volume	367
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/367/1/012038
Publication status	Published - 12 Jun 2018
Event	5th International Conference on Advanced Materials Sciences and Technology, ICAMST 2017 - Makassar, Indonesia Duration: 19 Sept 2017 → 20 Sept 2017

Keywords

and microsphere
hydrothermal
lithium-ion battery
lysine
α-FeO

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1088/1757-899X/367/1/012038

Cite this

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title = "Porous Fe2O3 Microspheres as Anode for Lithium-Ion Batteries",

abstract = "In this work, Fe2O3 was successfully synthesized by the hydrothermal process at low temperature. FeCl3.6H2O as precursor and variation of lysine as hydrolyzing agent were used to preparing Fe2O3. SEM images show that the morphology of Fe2O3 is porous microsphere with sizes in the range of (1 to 5) μm in diameter. The as-prepared Fe2O3 with the 2 M of lysine exhibits excellent cycling performance when used as the anode for lithium ion batteries, obtaining reversible discharge capacity of 172.33 mA•h•g-1 at 0.5 C after 50 cycles. It is attributed to the unique structure of porous microspheres providing a large surface area which maintains good electronic contact between particles during charge-discharge process. This result demonstrates that Fe2O3 porous microsphere has a high potential as anode material for application of lithium-ion battery.",

keywords = "and microsphere, hydrothermal, lithium-ion battery, lysine, α-FeO",

author = "L. Noerochim and Indra, {M. A.T.} and H. Purwaningsih and A. Subhan",

note = "Publisher Copyright: {\textcopyright} Published under licence by IOP Publishing Ltd.; 5th International Conference on Advanced Materials Sciences and Technology, ICAMST 2017 ; Conference date: 19-09-2017 Through 20-09-2017",

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T1 - Porous Fe2O3 Microspheres as Anode for Lithium-Ion Batteries

AU - Noerochim, L.

AU - Indra, M. A.T.

AU - Purwaningsih, H.

AU - Subhan, A.

N1 - Publisher Copyright: © Published under licence by IOP Publishing Ltd.

PY - 2018/6/12

Y1 - 2018/6/12

N2 - In this work, Fe2O3 was successfully synthesized by the hydrothermal process at low temperature. FeCl3.6H2O as precursor and variation of lysine as hydrolyzing agent were used to preparing Fe2O3. SEM images show that the morphology of Fe2O3 is porous microsphere with sizes in the range of (1 to 5) μm in diameter. The as-prepared Fe2O3 with the 2 M of lysine exhibits excellent cycling performance when used as the anode for lithium ion batteries, obtaining reversible discharge capacity of 172.33 mA•h•g-1 at 0.5 C after 50 cycles. It is attributed to the unique structure of porous microspheres providing a large surface area which maintains good electronic contact between particles during charge-discharge process. This result demonstrates that Fe2O3 porous microsphere has a high potential as anode material for application of lithium-ion battery.

AB - In this work, Fe2O3 was successfully synthesized by the hydrothermal process at low temperature. FeCl3.6H2O as precursor and variation of lysine as hydrolyzing agent were used to preparing Fe2O3. SEM images show that the morphology of Fe2O3 is porous microsphere with sizes in the range of (1 to 5) μm in diameter. The as-prepared Fe2O3 with the 2 M of lysine exhibits excellent cycling performance when used as the anode for lithium ion batteries, obtaining reversible discharge capacity of 172.33 mA•h•g-1 at 0.5 C after 50 cycles. It is attributed to the unique structure of porous microspheres providing a large surface area which maintains good electronic contact between particles during charge-discharge process. This result demonstrates that Fe2O3 porous microsphere has a high potential as anode material for application of lithium-ion battery.

KW - and microsphere

KW - hydrothermal

KW - lithium-ion battery

KW - lysine

KW - α-FeO

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