Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.)

Holilah Holilah; Lisman Suryanegara; Hasliza Bahruji; Zuratul Ain Abdul Hamid; Muhammad Sapto Wahyudi; Nanang Masruchin; Asranudin Asranudin; RH Fitri Faradilla; Edi Syafri; Alvina Tata Melenia; Stella Jovita; Reva Edra Nugraha; Didik Prasetyoko

doi:10.1016/j.cscee.2024.100922

Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.)

Holilah Holilah^*, Lisman Suryanegara, Hasliza Bahruji, Zuratul Ain Abdul Hamid, Muhammad Sapto Wahyudi, Nanang Masruchin, Asranudin Asranudin, RH Fitri Faradilla, Edi Syafri, Alvina Tata Melenia, Stella Jovita, Reva Edra Nugraha, Didik Prasetyoko^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Lactic acid recovery and reusability for hydrolysis of cellulose offers an economical method and produces fewer waste streams. Successful lactic acid recovery up to three recycle times efficiently hydrolyzed NCs with rod-shape morphology. However, after four cycles, the nanocrystalline cellulose yield reduced from 72.3 % to 48.2 %, forming large nanocelluloses with high crystalline index. Large-size nanocellulose with high zeta potential and thermal stability were obtained with increasing cycles due to inefficient acid diffusion into the rigid crystalline network compared to amorphous cellulose. This study offers a green pathway for hydrolysis nanocellulose using a less corrosive and low toxicity lactic acid than inorganic acids.

Original language	English
Article number	100922
Journal	Case Studies in Chemical and Environmental Engineering
Volume	10
DOIs	https://doi.org/10.1016/j.cscee.2024.100922
Publication status	Published - Dec 2024

Keywords

Nanocrystalline cellulose
acid recovery
hydrolysis
lactic acid
organic acid

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10.1016/j.cscee.2024.100922

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Holilah, H., Suryanegara, L., Bahruji, H., Hamid, Z. A. A., Wahyudi, M. S., Masruchin, N., Asranudin, A., Faradilla, RH. F., Syafri, E., Melenia, A. T., Jovita, S., Nugraha, R. E., & Prasetyoko, D. (2024). Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.). Case Studies in Chemical and Environmental Engineering, 10, Article 100922. https://doi.org/10.1016/j.cscee.2024.100922

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title = "Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.)",

abstract = "Lactic acid recovery and reusability for hydrolysis of cellulose offers an economical method and produces fewer waste streams. Successful lactic acid recovery up to three recycle times efficiently hydrolyzed NCs with rod-shape morphology. However, after four cycles, the nanocrystalline cellulose yield reduced from 72.3 % to 48.2 %, forming large nanocelluloses with high crystalline index. Large-size nanocellulose with high zeta potential and thermal stability were obtained with increasing cycles due to inefficient acid diffusion into the rigid crystalline network compared to amorphous cellulose. This study offers a green pathway for hydrolysis nanocellulose using a less corrosive and low toxicity lactic acid than inorganic acids.",

keywords = "Nanocrystalline cellulose, acid recovery, hydrolysis, lactic acid, organic acid",

author = "Holilah Holilah and Lisman Suryanegara and Hasliza Bahruji and Hamid, {Zuratul Ain Abdul} and Wahyudi, {Muhammad Sapto} and Nanang Masruchin and Asranudin Asranudin and Faradilla, {RH Fitri} and Edi Syafri and Melenia, {Alvina Tata} and Stella Jovita and Nugraha, {Reva Edra} and Didik Prasetyoko",

note = "Publisher Copyright: {\textcopyright} 2024 The Authors",

year = "2024",

month = dec,

doi = "10.1016/j.cscee.2024.100922",

language = "English",

volume = "10",

journal = "Case Studies in Chemical and Environmental Engineering",

issn = "2666-0164",

publisher = "Elsevier Ltd.",

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Holilah, H, Suryanegara, L, Bahruji, H, Hamid, ZAA, Wahyudi, MS, Masruchin, N, Asranudin, A, Faradilla, RHF, Syafri, E, Melenia, AT, Jovita, S, Nugraha, RE & Prasetyoko, D 2024, 'Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.)', Case Studies in Chemical and Environmental Engineering, vol. 10, 100922. https://doi.org/10.1016/j.cscee.2024.100922

TY - JOUR

T1 - Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.)

AU - Holilah, Holilah

AU - Suryanegara, Lisman

AU - Bahruji, Hasliza

AU - Hamid, Zuratul Ain Abdul

AU - Wahyudi, Muhammad Sapto

AU - Masruchin, Nanang

AU - Asranudin, Asranudin

AU - Faradilla, RH Fitri

AU - Syafri, Edi

AU - Melenia, Alvina Tata

AU - Jovita, Stella

AU - Nugraha, Reva Edra

AU - Prasetyoko, Didik

PY - 2024/12

Y1 - 2024/12

N2 - Lactic acid recovery and reusability for hydrolysis of cellulose offers an economical method and produces fewer waste streams. Successful lactic acid recovery up to three recycle times efficiently hydrolyzed NCs with rod-shape morphology. However, after four cycles, the nanocrystalline cellulose yield reduced from 72.3 % to 48.2 %, forming large nanocelluloses with high crystalline index. Large-size nanocellulose with high zeta potential and thermal stability were obtained with increasing cycles due to inefficient acid diffusion into the rigid crystalline network compared to amorphous cellulose. This study offers a green pathway for hydrolysis nanocellulose using a less corrosive and low toxicity lactic acid than inorganic acids.

AB - Lactic acid recovery and reusability for hydrolysis of cellulose offers an economical method and produces fewer waste streams. Successful lactic acid recovery up to three recycle times efficiently hydrolyzed NCs with rod-shape morphology. However, after four cycles, the nanocrystalline cellulose yield reduced from 72.3 % to 48.2 %, forming large nanocelluloses with high crystalline index. Large-size nanocellulose with high zeta potential and thermal stability were obtained with increasing cycles due to inefficient acid diffusion into the rigid crystalline network compared to amorphous cellulose. This study offers a green pathway for hydrolysis nanocellulose using a less corrosive and low toxicity lactic acid than inorganic acids.

KW - Nanocrystalline cellulose

KW - acid recovery

KW - hydrolysis

KW - lactic acid

KW - organic acid

UR - http://www.scopus.com/inward/record.url?scp=85203147429&partnerID=8YFLogxK

U2 - 10.1016/j.cscee.2024.100922

DO - 10.1016/j.cscee.2024.100922

M3 - Article

AN - SCOPUS:85203147429

SN - 2666-0164

VL - 10

JO - Case Studies in Chemical and Environmental Engineering

JF - Case Studies in Chemical and Environmental Engineering

M1 - 100922

ER -

Reusability of lactic acid on hydrolysis of nanocrystalline cellulose from pepper waste (piper nigrum L.)

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