Sulfation: A simple method to enhance the catalytic activity of TS-1 in epoxidation of 1-octene with aqueous hydrogen peroxide

Hadi Nur; Didik Prasetyoko; Zainab Ramli; Salasiah Endud

doi:10.1016/j.catcom.2004.09.007

Sulfation: A simple method to enhance the catalytic activity of TS-1 in epoxidation of 1-octene with aqueous hydrogen peroxide

Hadi Nur^*
, Didik Prasetyoko
, Zainab Ramli
, Salasiah Endud

^*Corresponding author for this work

Universiti Teknologi Malaysia

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Titanosilicalite (TS-1) has been successfully modified by sulfation to exhibit enhanced catalytic activity in the oxidation of I-octene with aquecous H₂O₂. A high activity of the sulfated TS-1 was related to modifications of the local environment of Ti active site upon interaction with the SO^2-₄

Original language	English
Pages (from-to)	725-728
Number of pages	4
Journal	Catalysis Communications
Volume	5
Issue number	12
DOIs	https://doi.org/10.1016/j.catcom.2004.09.007
Publication status	Published - Dec 2004
Externally published	Yes

Keywords

Enhancement of catalytic activity
Epoxidation
Sulfation
TS-1

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10.1016/j.catcom.2004.09.007

Cite this

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title = "Sulfation: A simple method to enhance the catalytic activity of TS-1 in epoxidation of 1-octene with aqueous hydrogen peroxide",

abstract = "Titanosilicalite (TS-1) has been successfully modified by sulfation to exhibit enhanced catalytic activity in the oxidation of I-octene with aquecous H2O2. A high activity of the sulfated TS-1 was related to modifications of the local environment of Ti active site upon interaction with the SO2-4",

keywords = "Enhancement of catalytic activity, Epoxidation, Sulfation, TS-1",

author = "Hadi Nur and Didik Prasetyoko and Zainab Ramli and Salasiah Endud",

note = "Funding Information: The authors thank the anonymous international referees for helpful suggestion and comments on an earlier draft. A research grant from the Ministry of Science Technology and Environment Malaysia (Grant No. 09-02-06-0057 SR0005/09-03) is gratefully acknowledged.",

year = "2004",

month = dec,

doi = "10.1016/j.catcom.2004.09.007",

language = "English",

volume = "5",

pages = "725--728",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

number = "12",

}

TY - JOUR

T1 - Sulfation

T2 - A simple method to enhance the catalytic activity of TS-1 in epoxidation of 1-octene with aqueous hydrogen peroxide

AU - Nur, Hadi

AU - Prasetyoko, Didik

AU - Ramli, Zainab

AU - Endud, Salasiah

N1 - Funding Information: The authors thank the anonymous international referees for helpful suggestion and comments on an earlier draft. A research grant from the Ministry of Science Technology and Environment Malaysia (Grant No. 09-02-06-0057 SR0005/09-03) is gratefully acknowledged.

PY - 2004/12

Y1 - 2004/12

N2 - Titanosilicalite (TS-1) has been successfully modified by sulfation to exhibit enhanced catalytic activity in the oxidation of I-octene with aquecous H2O2. A high activity of the sulfated TS-1 was related to modifications of the local environment of Ti active site upon interaction with the SO2-4

AB - Titanosilicalite (TS-1) has been successfully modified by sulfation to exhibit enhanced catalytic activity in the oxidation of I-octene with aquecous H2O2. A high activity of the sulfated TS-1 was related to modifications of the local environment of Ti active site upon interaction with the SO2-4

KW - Enhancement of catalytic activity

KW - Epoxidation

KW - Sulfation

KW - TS-1

UR - https://www.scopus.com/pages/publications/8444249309

U2 - 10.1016/j.catcom.2004.09.007

DO - 10.1016/j.catcom.2004.09.007

M3 - Article

AN - SCOPUS:8444249309

SN - 1566-7367

VL - 5

SP - 725

EP - 728

JO - Catalysis Communications

JF - Catalysis Communications

IS - 12

ER -

Sulfation: A simple method to enhance the catalytic activity of TS-1 in epoxidation of 1-octene with aqueous hydrogen peroxide

Abstract

Keywords

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