Polymeric complex [Fe(picolinate)3][MnNi(oxalate)3].CH3OH has been successfully synthesized using H-tube technique. The chemical composition of the synthesized product was determined by Elemental Analysis and Atomic Absorption Spectrometry. Infrared spectrum shows that the oxalate ligand acts as a bridging ligand. The crystalline product exists in the form of monoclinic structure and space group P21nas shown on the pattern of X-Ray Diffraction and has a similar structure with [Fe(bpp)2][MnCr(oxalate)3] complex. The magnetic susceptibility of the polymeric complex exhibits high spin and paramagnetic behavior.

Original languageEnglish
Pages (from-to)311-314
Number of pages4
JournalIndonesian Journal of Chemistry
Issue number3
Publication statusPublished - 2014


  • Bridging oxalate
  • Paramagnetic behavior
  • Picolinate ligand
  • Polymeric complex


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