Synthesis and characterization of [Fe(picolinate)3][MnNi(oxalate)3].CH3OH polymeric complex

Fahimah Martak; Djulia Onggo; Ismunandar; Agung Nugroho

doi:10.22146/ijc.21244

Synthesis and characterization of [Fe(picolinate)₃][MnNi(oxalate)₃].CH₃OH polymeric complex

Fahimah Martak^*
, Djulia Onggo
, Ismunandar
, Agung Nugroho

^*Corresponding author for this work

Bandung Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Polymeric complex [Fe(picolinate)₃][MnNi(oxalate)₃].CH₃OH has been successfully synthesized using H-tube technique. The chemical composition of the synthesized product was determined by Elemental Analysis and Atomic Absorption Spectrometry. Infrared spectrum shows that the oxalate ligand acts as a bridging ligand. The crystalline product exists in the form of monoclinic structure and space group P2_1nas shown on the pattern of X-Ray Diffraction and has a similar structure with [Fe(bpp)₂][MnCr(oxalate)₃] complex. The magnetic susceptibility of the polymeric complex exhibits high spin and paramagnetic behavior.

Original language	English
Pages (from-to)	311-314
Number of pages	4
Journal	Indonesian Journal of Chemistry
Volume	14
Issue number	3
DOIs	https://doi.org/10.22146/ijc.21244
Publication status	Published - 2014

Keywords

Bridging oxalate
Paramagnetic behavior
Picolinate ligand
Polymeric complex

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10.22146/ijc.21244

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title = "Synthesis and characterization of [Fe(picolinate)3][MnNi(oxalate)3].CH3OH polymeric complex",

abstract = "Polymeric complex [Fe(picolinate)3][MnNi(oxalate)3].CH3OH has been successfully synthesized using H-tube technique. The chemical composition of the synthesized product was determined by Elemental Analysis and Atomic Absorption Spectrometry. Infrared spectrum shows that the oxalate ligand acts as a bridging ligand. The crystalline product exists in the form of monoclinic structure and space group P21nas shown on the pattern of X-Ray Diffraction and has a similar structure with [Fe(bpp)2][MnCr(oxalate)3] complex. The magnetic susceptibility of the polymeric complex exhibits high spin and paramagnetic behavior.",

keywords = "Bridging oxalate, Paramagnetic behavior, Picolinate ligand, Polymeric complex",

author = "Fahimah Martak and Djulia Onggo and Ismunandar and Agung Nugroho",

year = "2014",

doi = "10.22146/ijc.21244",

language = "English",

volume = "14",

pages = "311--314",

journal = "Indonesian Journal of Chemistry",

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publisher = "Gadjah Mada University",

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T1 - Synthesis and characterization of [Fe(picolinate)3][MnNi(oxalate)3].CH3OH polymeric complex

AU - Martak, Fahimah

AU - Onggo, Djulia

AU - Ismunandar,

AU - Nugroho, Agung

PY - 2014

Y1 - 2014

N2 - Polymeric complex [Fe(picolinate)3][MnNi(oxalate)3].CH3OH has been successfully synthesized using H-tube technique. The chemical composition of the synthesized product was determined by Elemental Analysis and Atomic Absorption Spectrometry. Infrared spectrum shows that the oxalate ligand acts as a bridging ligand. The crystalline product exists in the form of monoclinic structure and space group P21nas shown on the pattern of X-Ray Diffraction and has a similar structure with [Fe(bpp)2][MnCr(oxalate)3] complex. The magnetic susceptibility of the polymeric complex exhibits high spin and paramagnetic behavior.

AB - Polymeric complex [Fe(picolinate)3][MnNi(oxalate)3].CH3OH has been successfully synthesized using H-tube technique. The chemical composition of the synthesized product was determined by Elemental Analysis and Atomic Absorption Spectrometry. Infrared spectrum shows that the oxalate ligand acts as a bridging ligand. The crystalline product exists in the form of monoclinic structure and space group P21nas shown on the pattern of X-Ray Diffraction and has a similar structure with [Fe(bpp)2][MnCr(oxalate)3] complex. The magnetic susceptibility of the polymeric complex exhibits high spin and paramagnetic behavior.

KW - Bridging oxalate

KW - Paramagnetic behavior

KW - Picolinate ligand

KW - Polymeric complex

UR - https://www.scopus.com/pages/publications/84911865019

U2 - 10.22146/ijc.21244

DO - 10.22146/ijc.21244

M3 - Article

AN - SCOPUS:84911865019

SN - 1411-9420

VL - 14

SP - 311

EP - 314

JO - Indonesian Journal of Chemistry

JF - Indonesian Journal of Chemistry

IS - 3

ER -

Synthesis and characterization of [Fe(picolinate)₃][MnNi(oxalate)₃].CH₃OH polymeric complex

Abstract

Keywords

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