Synthesis and magnetic properties of binuclear complex [N(n-C4H9)4][MniiFeiii(ox)3]

Fahimah Martak; Hamzah Fansuri; Sekarayu Dianing Putri

doi:10.22146/ijc.21377

Synthesis and magnetic properties of binuclear complex [N(n-C₄H₉)₄][MnⁱⁱFeⁱⁱⁱ(ox)₃]

Fahimah Martak^*
, Hamzah Fansuri
, Sekarayu Dianing Putri

^*Corresponding author for this work

Institut Teknologi Sepuluh Nopember

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Binuclear complex, [N(n-C₄H₉)₄][Mn^IIFeI^II(ox)₃] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C₄H₉)₄][Mn^IIFe^III(ox)₃] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C₄H₉)₄][Mn^IIFeI^II(ox)₃] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C₅H₁₁)₄][Mn^IIFe^III(ox)₃]. This behavior might be associated with the decreasing range among layers on polymeric network.

Original language	English
Pages (from-to)	89-93
Number of pages	5
Journal	Indonesian Journal of Chemistry
Volume	12
Issue number	1
DOIs	https://doi.org/10.22146/ijc.21377
Publication status	Published - 2012

Keywords

Binuclear complex
Iron complex
Magnetic properties
Oxalato network
X-ray powder diffraction

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@article{f7f7ffaad7ad413f92101277a0e37d14,

title = "Synthesis and magnetic properties of binuclear complex [N(n-C4H9)4][MniiFeiii(ox)3]",

abstract = "Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C4H9)4][MnIIFeIII(ox)3] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C5H11)4][MnIIFeIII(ox)3]. This behavior might be associated with the decreasing range among layers on polymeric network.",

keywords = "Binuclear complex, Iron complex, Magnetic properties, Oxalato network, X-ray powder diffraction",

author = "Fahimah Martak and Hamzah Fansuri and Putri, \{Sekarayu Dianing\}",

year = "2012",

doi = "10.22146/ijc.21377",

language = "English",

volume = "12",

pages = "89--93",

journal = "Indonesian Journal of Chemistry",

issn = "1411-9420",

publisher = "Gadjah Mada University",

number = "1",

}

TY - JOUR

T1 - Synthesis and magnetic properties of binuclear complex [N(n-C4H9)4][MniiFeiii(ox)3]

AU - Martak, Fahimah

AU - Fansuri, Hamzah

AU - Putri, Sekarayu Dianing

PY - 2012

Y1 - 2012

N2 - Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C4H9)4][MnIIFeIII(ox)3] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C5H11)4][MnIIFeIII(ox)3]. This behavior might be associated with the decreasing range among layers on polymeric network.

AB - Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C4H9)4][MnIIFeIII(ox)3] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C5H11)4][MnIIFeIII(ox)3]. This behavior might be associated with the decreasing range among layers on polymeric network.

KW - Binuclear complex

KW - Iron complex

KW - Magnetic properties

KW - Oxalato network

KW - X-ray powder diffraction

UR - https://www.scopus.com/pages/publications/84985945353

U2 - 10.22146/ijc.21377

DO - 10.22146/ijc.21377

M3 - Article

AN - SCOPUS:84985945353

SN - 1411-9420

VL - 12

SP - 89

EP - 93

JO - Indonesian Journal of Chemistry

JF - Indonesian Journal of Chemistry

IS - 1

ER -

Synthesis and magnetic properties of binuclear complex [N(n-C₄H₉)₄][MnⁱⁱFeⁱⁱⁱ(ox)₃]

Abstract

Keywords

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