Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material

Ni’matul Waladiya Kurniasari; Prida Novarita Trisanti; Kukuh Dwiputra Hernugrahanto; Ferdiansyah

doi:10.1063/5.0115493

Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material

Ni’matul Waladiya Kurniasari, Prida Novarita Trisanti, Kukuh Dwiputra Hernugrahanto, Ferdiansyah, Sumarno^*

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The production of Polymethyl Methacrylate (PMMA) play an important role in many orthopedic surgery as the main compound for bone cements. Synthesis of Polymethyl Methacrylate (PMMA) was produced by suspension polymerization. Purified Methyl Methacrylate (MMA) and benzoyl peroxide (BPO) as an initiator was added to the reactor after the heating process reaches a temperature of 85^oC where Polyvinyl Alcohol (PVA) and water homogenized first. Due to the use of PMMA products in medical field, it is desirable to use non-toxic solvents for the purification process. PMMA purified by removing impurities MMA, BPO, and PVA with a sequent solvent of water, and a mixture of ethanol and water with 1:1 ratio. Then, PMMA powder filtered and dried. Characterization of PMMA product resulted molecular weight of 512x10³ Da with particle size 77.256 μm, glass transition temperature (Tg) of 119.15^oC, and compressive strength 80.12 MPa.

Original language	English
Title of host publication	Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology
Editors	Adibah Izzati Daud, Azduwin Khasri, Noor Ainee Zainol, Nur Izzati Iberahim, Azlinda Abdul Ghani, Nor Munirah Rohaizad
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735444805
DOIs	https://doi.org/10.1063/5.0115493
Publication status	Published - 9 Jun 2023
Event	1st International Conference of Chemical Science, Engineering, and Technology, ICO-CSET 2021 - Virtual, Online Duration: 6 Sept 2021 → 7 Sept 2021

Publication series

Name	AIP Conference Proceedings
Volume	2703
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	1st International Conference of Chemical Science, Engineering, and Technology, ICO-CSET 2021
City	Virtual, Online
Period	6/09/21 → 7/09/21

Keywords

Bone cement
polymethyl methacrylate
purification
suspension polymerization
synthesis

Access to Document

10.1063/5.0115493

Cite this

Kurniasari, N. W., Trisanti, P. N., Hernugrahanto, K. D., Ferdiansyah, & Sumarno (2023). Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material. In A. I. Daud, A. Khasri, N. A. Zainol, N. I. Iberahim, A. A. Ghani, & N. M. Rohaizad (Eds.), Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology Article 050004 (AIP Conference Proceedings; Vol. 2703). American Institute of Physics Inc.. https://doi.org/10.1063/5.0115493

Kurniasari, Ni’matul Waladiya ; Trisanti, Prida Novarita ; Hernugrahanto, Kukuh Dwiputra et al. / Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material. Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology. editor / Adibah Izzati Daud ; Azduwin Khasri ; Noor Ainee Zainol ; Nur Izzati Iberahim ; Azlinda Abdul Ghani ; Nor Munirah Rohaizad. American Institute of Physics Inc., 2023. (AIP Conference Proceedings).

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title = "Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material",

abstract = "The production of Polymethyl Methacrylate (PMMA) play an important role in many orthopedic surgery as the main compound for bone cements. Synthesis of Polymethyl Methacrylate (PMMA) was produced by suspension polymerization. Purified Methyl Methacrylate (MMA) and benzoyl peroxide (BPO) as an initiator was added to the reactor after the heating process reaches a temperature of 85oC where Polyvinyl Alcohol (PVA) and water homogenized first. Due to the use of PMMA products in medical field, it is desirable to use non-toxic solvents for the purification process. PMMA purified by removing impurities MMA, BPO, and PVA with a sequent solvent of water, and a mixture of ethanol and water with 1:1 ratio. Then, PMMA powder filtered and dried. Characterization of PMMA product resulted molecular weight of 512x103 Da with particle size 77.256 μm, glass transition temperature (Tg) of 119.15oC, and compressive strength 80.12 MPa.",

keywords = "Bone cement, polymethyl methacrylate, purification, suspension polymerization, synthesis",

author = "Kurniasari, {Ni{\textquoteright}matul Waladiya} and Trisanti, {Prida Novarita} and Hernugrahanto, {Kukuh Dwiputra} and Ferdiansyah and Sumarno",

note = "Publisher Copyright: {\textcopyright} 2023 American Institute of Physics Inc.. All rights reserved.; 1st International Conference of Chemical Science, Engineering, and Technology, ICO-CSET 2021 ; Conference date: 06-09-2021 Through 07-09-2021",

year = "2023",

month = jun,

day = "9",

doi = "10.1063/5.0115493",

language = "English",

series = "AIP Conference Proceedings",

publisher = "American Institute of Physics Inc.",

editor = "Daud, {Adibah Izzati} and Azduwin Khasri and Zainol, {Noor Ainee} and Iberahim, {Nur Izzati} and Ghani, {Azlinda Abdul} and Rohaizad, {Nor Munirah}",

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Kurniasari, NW, Trisanti, PN, Hernugrahanto, KD, Ferdiansyah, & Sumarno 2023, Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material. in AI Daud, A Khasri, NA Zainol, NI Iberahim, AA Ghani & NM Rohaizad (eds), Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology., 050004, AIP Conference Proceedings, vol. 2703, American Institute of Physics Inc., 1st International Conference of Chemical Science, Engineering, and Technology, ICO-CSET 2021, Virtual, Online, 6/09/21. https://doi.org/10.1063/5.0115493

Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material. / Kurniasari, Ni’matul Waladiya; Trisanti, Prida Novarita; Hernugrahanto, Kukuh Dwiputra et al.
Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology. ed. / Adibah Izzati Daud; Azduwin Khasri; Noor Ainee Zainol; Nur Izzati Iberahim; Azlinda Abdul Ghani; Nor Munirah Rohaizad. American Institute of Physics Inc., 2023. 050004 (AIP Conference Proceedings; Vol. 2703).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material

AU - Kurniasari, Ni’matul Waladiya

AU - Trisanti, Prida Novarita

AU - Hernugrahanto, Kukuh Dwiputra

AU - Ferdiansyah,

AU - Sumarno,

PY - 2023/6/9

Y1 - 2023/6/9

N2 - The production of Polymethyl Methacrylate (PMMA) play an important role in many orthopedic surgery as the main compound for bone cements. Synthesis of Polymethyl Methacrylate (PMMA) was produced by suspension polymerization. Purified Methyl Methacrylate (MMA) and benzoyl peroxide (BPO) as an initiator was added to the reactor after the heating process reaches a temperature of 85oC where Polyvinyl Alcohol (PVA) and water homogenized first. Due to the use of PMMA products in medical field, it is desirable to use non-toxic solvents for the purification process. PMMA purified by removing impurities MMA, BPO, and PVA with a sequent solvent of water, and a mixture of ethanol and water with 1:1 ratio. Then, PMMA powder filtered and dried. Characterization of PMMA product resulted molecular weight of 512x103 Da with particle size 77.256 μm, glass transition temperature (Tg) of 119.15oC, and compressive strength 80.12 MPa.

AB - The production of Polymethyl Methacrylate (PMMA) play an important role in many orthopedic surgery as the main compound for bone cements. Synthesis of Polymethyl Methacrylate (PMMA) was produced by suspension polymerization. Purified Methyl Methacrylate (MMA) and benzoyl peroxide (BPO) as an initiator was added to the reactor after the heating process reaches a temperature of 85oC where Polyvinyl Alcohol (PVA) and water homogenized first. Due to the use of PMMA products in medical field, it is desirable to use non-toxic solvents for the purification process. PMMA purified by removing impurities MMA, BPO, and PVA with a sequent solvent of water, and a mixture of ethanol and water with 1:1 ratio. Then, PMMA powder filtered and dried. Characterization of PMMA product resulted molecular weight of 512x103 Da with particle size 77.256 μm, glass transition temperature (Tg) of 119.15oC, and compressive strength 80.12 MPa.

KW - Bone cement

KW - polymethyl methacrylate

KW - purification

KW - suspension polymerization

KW - synthesis

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U2 - 10.1063/5.0115493

DO - 10.1063/5.0115493

M3 - Conference contribution

AN - SCOPUS:85163843806

T3 - AIP Conference Proceedings

BT - Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology

A2 - Daud, Adibah Izzati

A2 - Khasri, Azduwin

A2 - Zainol, Noor Ainee

A2 - Iberahim, Nur Izzati

A2 - Ghani, Azlinda Abdul

A2 - Rohaizad, Nor Munirah

PB - American Institute of Physics Inc.

T2 - 1st International Conference of Chemical Science, Engineering, and Technology, ICO-CSET 2021

Y2 - 6 September 2021 through 7 September 2021

ER -

Kurniasari NW, Trisanti PN, Hernugrahanto KD, Ferdiansyah , Sumarno. Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material. In Daud AI, Khasri A, Zainol NA, Iberahim NI, Ghani AA, Rohaizad NM, editors, Proceedings of the 1st International Conference of Chemical Science, Engineering, and Technology. American Institute of Physics Inc. 2023. 050004. (AIP Conference Proceedings). doi: 10.1063/5.0115493

Synthesis and Purification Process of PMMA by Suspension Polymerization for Bone Cement Material

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