Synthesis of ZIF-67 in the presence of acetic acid as methyl orange adsorbent

Dety O. Sulistiono, Ratna Ediati*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

4 Citations (Scopus)

Abstract

Zeolitic Imidazolate Framework-67 (ZIF-67) materials have successfully been synthesized in aqueous solution at ratios of Co2+, 2-methylimidazole, and triethylamine as a deprotonating agent, i.e. 1:5:5; 1:10:5 and 1:10:10, in the presence and the absence of acetic acid. The XRD patterns of all synthesized materials showed peak characteristics at 2 thetas which were the same as simulated ZIF -67. The results of FTIR analysis showed appearance absorption bands at the same wavenumber for all synthesized materials. The presence of acetic acid, however, resulted in the decrease in intensities of the XRD peaks and altered the surface morphology to become irregular. All materials were examined their performance as an adsorbent for the removal of methyl orange in water. It was found that the highest adsorption capacity of 214 mg/g was shown by ZIF-67(1:10:5AA). Pseudo-second order kinetics and Langmuir isotherms correspond to all synthesized materials.

Original languageEnglish
Title of host publication4th International Seminar on Chemistry
EditorsYuly Kusumawati, Adi Setyo Purnomo
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735441002
DOIs
Publication statusPublished - 24 Jun 2021
Event4th International Seminar on Chemistry, ISoC 2021 - Surabaya, Indonesia
Duration: 7 Oct 20208 Oct 2020

Publication series

NameAIP Conference Proceedings
Volume2349
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference4th International Seminar on Chemistry, ISoC 2021
Country/TerritoryIndonesia
CitySurabaya
Period7/10/208/10/20

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