Synthesize of LiMn2O4from manganese ore as cathode materials in lithium ion battery

Haryudini Arsa Putri, Alfikri Khair, Yatim Lailun Ni'Mah, Suprapto Suprapto*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Citations (Scopus)

Abstract

In this work, lithium ion battery cathode material (LiMn2O4) has been synthesized from Li2CO3 as a source of Li and manganese ore (pyrolusite) as a source of MnO2. Manganese ore was characterized using X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD). XRF results showed that manganese ore contains 89.35% MnO. XRD diffractogram showed MnO2 peaks in accordance with JCPDS no. 24-0735. Manganese ore was leached using hydrofluoric acid and nitric acid to remove silica and other impurities. Leaching optimization was carried out using Response Surface Methodology (RSM) with Box-Bahken Design. The optimization showed that the highest MnO2 recovery from acid leaching was 95.73%. All the leaching residue contain MnO2 at 100% ranges. The optimum acid leaching condition was obtained by leaching 0.5 grams of manganese ore in 20 mL HNO3 at 80°C for 6 hours. LiMn2O4 was synthesized using a solid state reaction at 900 °C. The LiMn2O4 that obtained was applied as cathode materials characterized using cyclic voltammetry (CV), charge-discharge (CD) and Electrochemical Impedance Spectroscopy (EIS).

Original languageEnglish
Title of host publication3rd International Seminar on Chemical Education
Subtitle of host publicationTrends, Applications, Changes in Chemical Education for the 4.0 Industrial Revolution
EditorsIs Fatimah, Muhaimin, Muhammad Miqdam Musawwa
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735419889
DOIs
Publication statusPublished - 21 Apr 2020
Event3rd International Seminar on Chemical Education: Trends, Applications, Changes in Chemical Education for the 4.0 Industrial Revolution, ISCE 2019 - Yogyakarta, Indonesia
Duration: 17 Sept 2019 → …

Publication series

NameAIP Conference Proceedings
Volume2229
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference3rd International Seminar on Chemical Education: Trends, Applications, Changes in Chemical Education for the 4.0 Industrial Revolution, ISCE 2019
Country/TerritoryIndonesia
CityYogyakarta
Period17/09/19 → …

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