TY - GEN
T1 - Synthesize of LiMn2O4from used dry cell paste as cathode materials in lithium ion battery
AU - Ni'Mah, Yatim Lailun
AU - Median, Camelia Maharani
AU - Savitri, Diajeng Aulina
AU - Suprapto,
N1 - Publisher Copyright:
© 2020 Author(s).
PY - 2020/4/21
Y1 - 2020/4/21
N2 - Lithium ion battery (LiMn2O4) cathode materials have been successfully synthesized using LiCl as a source of Li and MnO2 from waste batteries as a source of Mn. This research aims were to determine the optimum parameters for dry cell paste acid leaching. The parameters that optimized i.e. mass variation of dry cell battery, H2SO4 concentration, and reaction time. The dry cell paste was analyzed using X-Ray Fluorescence (XRF) to determine its composition. The synthesis of LiMn2O4 was carried out by solid state reaction (SSR). MnO2 that obtained from acid leaching was mixed with LiCl with a mole ratio of MnO2 and LiCl (2:1). The mixture then calcined at 750°C for 4 hours followed by sintering at 900°C for 6 hours. LiMn2O4 was characterized by X-Ray Diffraction (XRD). The cyclic voltammetry test on a battery with LiMn2O4 cathode materials obtained shows that the peak pairs of reduction and oxidation were 3.3 V and 4.3 V. The LiMn2O4 charge-discharge test shows that the capacity of the battery were 4.12 mAh/g and 2.12 mAh/g with efficiency of 50.97 %.
AB - Lithium ion battery (LiMn2O4) cathode materials have been successfully synthesized using LiCl as a source of Li and MnO2 from waste batteries as a source of Mn. This research aims were to determine the optimum parameters for dry cell paste acid leaching. The parameters that optimized i.e. mass variation of dry cell battery, H2SO4 concentration, and reaction time. The dry cell paste was analyzed using X-Ray Fluorescence (XRF) to determine its composition. The synthesis of LiMn2O4 was carried out by solid state reaction (SSR). MnO2 that obtained from acid leaching was mixed with LiCl with a mole ratio of MnO2 and LiCl (2:1). The mixture then calcined at 750°C for 4 hours followed by sintering at 900°C for 6 hours. LiMn2O4 was characterized by X-Ray Diffraction (XRD). The cyclic voltammetry test on a battery with LiMn2O4 cathode materials obtained shows that the peak pairs of reduction and oxidation were 3.3 V and 4.3 V. The LiMn2O4 charge-discharge test shows that the capacity of the battery were 4.12 mAh/g and 2.12 mAh/g with efficiency of 50.97 %.
UR - http://www.scopus.com/inward/record.url?scp=85101042869&partnerID=8YFLogxK
U2 - 10.1063/5.0002655
DO - 10.1063/5.0002655
M3 - Conference contribution
AN - SCOPUS:85101042869
T3 - AIP Conference Proceedings
BT - 3rd International Seminar on Chemical Education
A2 - Fatimah, Is
A2 - Muhaimin, null
A2 - Musawwa, Muhammad Miqdam
PB - American Institute of Physics Inc.
T2 - 3rd International Seminar on Chemical Education: Trends, Applications, Changes in Chemical Education for the 4.0 Industrial Revolution, ISCE 2019
Y2 - 17 September 2019
ER -
