Ternary liquid-liquid equilibria of dimethyl carbonate + 2-propanol + water system at 303.15 and 313.15 K

Rizqy Romadhona Ginting, Asalil Mustain, Rizki Tetrisyanda, Ignatius Gunardi, Gede Wibawa*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

7 Citations (Scopus)

Abstract

In this work, liquid-liquid equilibria data of dimethyl carbonate (DMC) + 2-propanol + water system were accurately determined at 303.15 and 313.15?K using stirred and jacketed equilibrium cell under atmospheric pressure. The reliabilities of the experimental data were confirmed using Bachman-Brown correlation giving r-squared value of 0.9993 and 0.9983 at 303.15 and 313.15?K, respectively. Experimental data obtained in this work exhibit Treybal's Type I ternary phase behavior. The selectivity and distribution coefficient of DMC increases with addition of DMC concentration in the organic phase. On the other hand, the effect of temperature to phase boundary was found to be not significant. The data were correlated well using the Non-Random Two Liquid (NRTL) and Universal Quasi-Chemical (UNIQUAC) activity coefficient models with root-mean-square deviation of 1.5% and 1.3%, respectively.

Original languageEnglish
Title of host publicationInternational Conference of Chemical and Material Engineering, ICCME 2015
Subtitle of host publicationGreen Technology for Sustainable Chemical Products and Processes
EditorsFerry Iskandar, Hadiyanto, Arief Budiman, Hadi Nur, Suryadi Ismadji
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735413467
DOIs
Publication statusPublished - 29 Dec 2015
Event2nd International Conference of Chemical and Material Engineering: Green Technology for Sustainable Chemical Products and Processes, ICCME 2015 - Semarang, Indonesia
Duration: 29 Sept 201530 Sept 2015

Publication series

NameAIP Conference Proceedings
Volume1699
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference2nd International Conference of Chemical and Material Engineering: Green Technology for Sustainable Chemical Products and Processes, ICCME 2015
Country/TerritoryIndonesia
CitySemarang
Period29/09/1530/09/15

Keywords

  • 2-propanol
  • dimethyl carbonate
  • gasoline additives
  • liquid-liquid equilibria
  • oxygenated compound

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