The rule of carrier gas flow rate to Li+ diffusivity of LiFePo4 particles as lithium battery application

Abdul Halim; Firqi A. Kusumandari; Heru Setyawan; Sugeng Winardi; Nur A. Siddiq; Ahmad F. Adziimaa; Dyah Sawitri

doi:10.1109/ICRESE.2013.6927810

The rule of carrier gas flow rate to Li⁺ diffusivity of LiFePo₄ particles as lithium battery application

Abdul Halim, Firqi A. Kusumandari, Widiyastuti, Heru Setyawan, Sugeng Winardi, Nur A. Siddiq, Ahmad F. Adziimaa, Dyah Sawitri

Institut Teknologi Sepuluh Nopember

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

The effect carrier gas flow rate to particles characteristic was studied experimentally and numerically. Experimental investigation was carried out using flame spray pyrolysis method. LPG and free air were used as fuel and oxidizer, respectively. LiOH, (NH₄)₂HPO₄ and FePO₄.7H₂O were used as anorganic precursor. Numerical method was studied using ANSYS FLUENT 14.5 with finite volume technique. Annealing process was followed to increase the particles crystallinity. The results indicated that increasing the carrier gas flow rate caused decreasing the flame temperature. The crystallinity of particles increased proportional to flame temperature rising. Scanning Electrostatic Microscopy (SEM) revealed that the particles have sphere morphology. The particle size was decreased by increasing carrier gas flow rate. Fourier Transform Infrared (FTIR) showed the PO₄ functional group. Increasing carrier gas flow rate tend to enhance the transmittance intensity. The diffusivity coefficient obtained for carrier gas flow rate 1, 2 and 3 liter/min were 2.56 × 10^-9, 1.11 × 10^-9 and 9.26 × 10^-11cm²s^-1 respectively.

Original language	English
Title of host publication	Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	170-174
Number of pages	5
ISBN (Electronic)	9781479920754
DOIs	https://doi.org/10.1109/ICRESE.2013.6927810
Publication status	Published - 16 Oct 2014
Event	2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013 - Coimbatore, India Duration: 5 Dec 2013 → 6 Dec 2013

Publication series

Name	Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013

Conference

Conference	2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013
Country/Territory	India
City	Coimbatore
Period	5/12/13 → 6/12/13

Keywords

Flame spray pyrolysis
Li Battery
LiFePO4
diffusivity coefficient

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1109/ICRESE.2013.6927810

Cite this

Halim, A., Kusumandari, F. A., Widiyastuti , Setyawan, H., Winardi, S., Siddiq, N. A., Adziimaa, A. F., & Sawitri, D. (2014). The rule of carrier gas flow rate to Li⁺ diffusivity of LiFePo₄ particles as lithium battery application. In Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013 (pp. 170-174). Article 6927810 (Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/ICRESE.2013.6927810

Halim, Abdul ; Kusumandari, Firqi A. ; Widiyastuti et al. / The rule of carrier gas flow rate to Li⁺ diffusivity of LiFePo₄ particles as lithium battery application. Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013. Institute of Electrical and Electronics Engineers Inc., 2014. pp. 170-174 (Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013).

@inproceedings{b619ed8337af4dd7b54e1fa59bc3f26a,

title = "The rule of carrier gas flow rate to Li+ diffusivity of LiFePo4 particles as lithium battery application",

abstract = "The effect carrier gas flow rate to particles characteristic was studied experimentally and numerically. Experimental investigation was carried out using flame spray pyrolysis method. LPG and free air were used as fuel and oxidizer, respectively. LiOH, (NH4)2HPO4 and FePO4.7H2O were used as anorganic precursor. Numerical method was studied using ANSYS FLUENT 14.5 with finite volume technique. Annealing process was followed to increase the particles crystallinity. The results indicated that increasing the carrier gas flow rate caused decreasing the flame temperature. The crystallinity of particles increased proportional to flame temperature rising. Scanning Electrostatic Microscopy (SEM) revealed that the particles have sphere morphology. The particle size was decreased by increasing carrier gas flow rate. Fourier Transform Infrared (FTIR) showed the PO4 functional group. Increasing carrier gas flow rate tend to enhance the transmittance intensity. The diffusivity coefficient obtained for carrier gas flow rate 1, 2 and 3 liter/min were 2.56 × 10-9, 1.11 × 10-9 and 9.26 × 10-11cm2s-1 respectively.",

keywords = "Flame spray pyrolysis, Li Battery, LiFePO4, diffusivity coefficient",

author = "Abdul Halim and Kusumandari, {Firqi A.} and Widiyastuti and Heru Setyawan and Sugeng Winardi and Siddiq, {Nur A.} and Adziimaa, {Ahmad F.} and Dyah Sawitri",

note = "Publisher Copyright: {\textcopyright} 2013 IEEE.; 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013 ; Conference date: 05-12-2013 Through 06-12-2013",

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doi = "10.1109/ICRESE.2013.6927810",

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Halim, A, Kusumandari, FA, Widiyastuti, , Setyawan, H, Winardi, S, Siddiq, NA, Adziimaa, AF & Sawitri, D 2014, The rule of carrier gas flow rate to Li⁺ diffusivity of LiFePo₄ particles as lithium battery application. in Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013., 6927810, Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013, Institute of Electrical and Electronics Engineers Inc., pp. 170-174, 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013, Coimbatore, India, 5/12/13. https://doi.org/10.1109/ICRESE.2013.6927810

The rule of carrier gas flow rate to Li⁺ diffusivity of LiFePo₄ particles as lithium battery application. / Halim, Abdul; Kusumandari, Firqi A.; Widiyastuti et al.
Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013. Institute of Electrical and Electronics Engineers Inc., 2014. p. 170-174 6927810 (Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - The rule of carrier gas flow rate to Li+ diffusivity of LiFePo4 particles as lithium battery application

AU - Halim, Abdul

AU - Kusumandari, Firqi A.

AU - Widiyastuti,

AU - Setyawan, Heru

AU - Winardi, Sugeng

AU - Siddiq, Nur A.

AU - Adziimaa, Ahmad F.

AU - Sawitri, Dyah

PY - 2014/10/16

Y1 - 2014/10/16

N2 - The effect carrier gas flow rate to particles characteristic was studied experimentally and numerically. Experimental investigation was carried out using flame spray pyrolysis method. LPG and free air were used as fuel and oxidizer, respectively. LiOH, (NH4)2HPO4 and FePO4.7H2O were used as anorganic precursor. Numerical method was studied using ANSYS FLUENT 14.5 with finite volume technique. Annealing process was followed to increase the particles crystallinity. The results indicated that increasing the carrier gas flow rate caused decreasing the flame temperature. The crystallinity of particles increased proportional to flame temperature rising. Scanning Electrostatic Microscopy (SEM) revealed that the particles have sphere morphology. The particle size was decreased by increasing carrier gas flow rate. Fourier Transform Infrared (FTIR) showed the PO4 functional group. Increasing carrier gas flow rate tend to enhance the transmittance intensity. The diffusivity coefficient obtained for carrier gas flow rate 1, 2 and 3 liter/min were 2.56 × 10-9, 1.11 × 10-9 and 9.26 × 10-11cm2s-1 respectively.

AB - The effect carrier gas flow rate to particles characteristic was studied experimentally and numerically. Experimental investigation was carried out using flame spray pyrolysis method. LPG and free air were used as fuel and oxidizer, respectively. LiOH, (NH4)2HPO4 and FePO4.7H2O were used as anorganic precursor. Numerical method was studied using ANSYS FLUENT 14.5 with finite volume technique. Annealing process was followed to increase the particles crystallinity. The results indicated that increasing the carrier gas flow rate caused decreasing the flame temperature. The crystallinity of particles increased proportional to flame temperature rising. Scanning Electrostatic Microscopy (SEM) revealed that the particles have sphere morphology. The particle size was decreased by increasing carrier gas flow rate. Fourier Transform Infrared (FTIR) showed the PO4 functional group. Increasing carrier gas flow rate tend to enhance the transmittance intensity. The diffusivity coefficient obtained for carrier gas flow rate 1, 2 and 3 liter/min were 2.56 × 10-9, 1.11 × 10-9 and 9.26 × 10-11cm2s-1 respectively.

KW - Flame spray pyrolysis

KW - Li Battery

KW - LiFePO4

KW - diffusivity coefficient

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U2 - 10.1109/ICRESE.2013.6927810

DO - 10.1109/ICRESE.2013.6927810

M3 - Conference contribution

AN - SCOPUS:84919666843

T3 - Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013

SP - 170

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BT - Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013

PB - Institute of Electrical and Electronics Engineers Inc.

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Halim A, Kusumandari FA, Widiyastuti , Setyawan H, Winardi S, Siddiq NA et al. The rule of carrier gas flow rate to Li⁺ diffusivity of LiFePo₄ particles as lithium battery application. In Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013. Institute of Electrical and Electronics Engineers Inc. 2014. p. 170-174. 6927810. (Proceedings - 2013 International Conference on Renewable Energy and Sustainable Energy, ICRESE 2013). doi: 10.1109/ICRESE.2013.6927810