Tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide

Didik Prasetyoko; Hamzah Fansuri; Zainab Ramli; Salasiah Endud; Hadi Nur

doi:10.1007/s10562-008-9727-7

Tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide

Didik Prasetyoko^*
, Hamzah Fansuri
, Zainab Ramli
, Salasiah Endud
, Hadi Nur

^*Corresponding author for this work

Universiti Teknologi Malaysia

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Tungsten oxides (WO₃) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H₂O₂ in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts.

Original language	English
Pages (from-to)	177-182
Number of pages	6
Journal	Catalysis Letters
Volume	128
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-008-9727-7
Publication status	Published - Mar 2009

Keywords

Epoxidation
Titanosilicalite-1
Tungsten oxides

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10.1007/s10562-008-9727-7

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title = "Tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide",

abstract = "Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts.",

keywords = "Epoxidation, Titanosilicalite-1, Tungsten oxides",

author = "Didik Prasetyoko and Hamzah Fansuri and Zainab Ramli and Salasiah Endud and Hadi Nur",

note = "Funding Information: Acknowledgments We gratefully acknowledge funding from the Ministry of Science Technology and Innovation Malaysia (MOSTI), under IRPA grant No. 09-02-06-0057 SR0005/09-03 and Directorate General of Higher Education, Indonesia, under Hibah Kompetensi grant No. 1108/I2.7/PM/2008.",

year = "2009",

month = mar,

doi = "10.1007/s10562-008-9727-7",

language = "English",

volume = "128",

pages = "177--182",

journal = "Catalysis Letters",

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T1 - Tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide

AU - Prasetyoko, Didik

AU - Fansuri, Hamzah

AU - Ramli, Zainab

AU - Endud, Salasiah

AU - Nur, Hadi

N1 - Funding Information: Acknowledgments We gratefully acknowledge funding from the Ministry of Science Technology and Innovation Malaysia (MOSTI), under IRPA grant No. 09-02-06-0057 SR0005/09-03 and Directorate General of Higher Education, Indonesia, under Hibah Kompetensi grant No. 1108/I2.7/PM/2008.

PY - 2009/3

Y1 - 2009/3

N2 - Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts.

AB - Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts.

KW - Epoxidation

KW - Titanosilicalite-1

KW - Tungsten oxides

UR - https://www.scopus.com/pages/publications/59549086284

U2 - 10.1007/s10562-008-9727-7

DO - 10.1007/s10562-008-9727-7

M3 - Article

AN - SCOPUS:59549086284

SN - 1011-372X

VL - 128

SP - 177

EP - 182

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

Tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide

Abstract

Keywords

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