Use of ZrO 2 supported on bamboo leaf ash as a heterogeneous catalyst in microwave-assisted biodiesel conversion

Is Fatimah*, Dwiarso Rubiyanto, Ana Taushiyah, Fitri Badriatun Najah, Ulil Azmi, Yoke Leng Sim

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

51 Citations (Scopus)

Abstract

In this research, bamboo leaf ash was utilized as ZrO 2 support for heterogeneous catalyst application. The preparation of ZrO 2 -supported bamboo leaf ash (ZrO 2 /BLA) was conducted by the impregnation method with a metal content of 20%wt. The physicochemical characterization of the prepared material was studied using XRD, gas sorption analysis, FTIR and SEM-EDX. The material was tested for use in the biodiesel conversion of soybean oil under microwave-assisted conversion. The results show that the physicochemical characteristics of ZrO 2 /BLA facilitated the catalytic activity in biodiesel conversion. The effects of the reaction method, the methanol-to-oil molar ratio, and the catalyst weight were investigated. The microwave-assisted method gave yields comparable to those obtained via the reflux method in less time. The optimized conditions of fatty acid methyl ester (FAME) production using the microwave-assisted reaction method were a 15:1 methanol-to-oil molar ratio, 30 min of reaction time and 12%wt. catalyst weight. The catalyst exhibited reusability properties, as indicated by its relatively similar yields, initial rates and turnover frequencies observed when fresh and reused catalysts were used.

Original languageEnglish
Article number100129
JournalSustainable Chemistry and Pharmacy
Volume12
DOIs
Publication statusPublished - Jun 2019
Externally publishedYes

Keywords

  • Bamboo leaves
  • Biodiesel
  • Heterogeneous catalysts
  • Zirconia

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