TY - JOUR
T1 - Utilization of polystyrene waste with biodiesel from cooking oil waste as feedstock in catalytic cracking using Al-MCM-41/Ceramic and Pd/Al-MCM-41/Ceramic catalysts
AU - Juwono, H.
AU - Pamungkas, F. S.
AU - Elliyanti, A.
AU - Assari, A.
AU - Dermawan, A. H.
AU - Nurfitriyah, A.
N1 - Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2020/4/7
Y1 - 2020/4/7
N2 - Liquid fuel from polystyrene plastic waste with co-reactant of cooking oil waste biodiesel has been obtained. The catalysts used in catalytic cracking are Al-MCM-41/ceramic and Pd/Al-MCM-41/ceramic catalysts. Morphology and elemental composition were observed with SEM EDX, the crystal structure observed with XRD, surface area and pore volume were analyzed by Nitrogen adsorption-desorption each calculated by BET and BJH method, acidity determined by FTIR-Pyridine, and temperature resistance analyzed by DTA. The results of catalytic cracking were investigated using Gas Chromatography-Mass Spectroscopy (GC-MS). Characterization of the catalyst showed that acidity was reduced because the Si/Al ratio was reduced after the impregnation and the surface area of Al-MCM-41/ceramics also decreased. SEM EDX shows that the composition of the carbon element on the surface of the Pd/Al- MCM-41/ceramic catalyst is smaller compared to the Al-MCM-41/ceramic catalyst. The results of the GC-MS characterization of liquid fuels from catalytic cracking using Pd/Al- MCM-41/ceramics catalyst, have a percentage of gasoline fraction (C7-C12) of 74.9% at 120 minutes cracking. The mixture of fuel from the addition of 150 mL liquid fuel resulting from catalytic cracking with Pd/Al-MCM-41/ceramic catalyst has the highest calorific value of 19160.61 (kcal/kg) and the performance of the gasoline Genset engine has the highest thermal efficiency of 28.27%.
AB - Liquid fuel from polystyrene plastic waste with co-reactant of cooking oil waste biodiesel has been obtained. The catalysts used in catalytic cracking are Al-MCM-41/ceramic and Pd/Al-MCM-41/ceramic catalysts. Morphology and elemental composition were observed with SEM EDX, the crystal structure observed with XRD, surface area and pore volume were analyzed by Nitrogen adsorption-desorption each calculated by BET and BJH method, acidity determined by FTIR-Pyridine, and temperature resistance analyzed by DTA. The results of catalytic cracking were investigated using Gas Chromatography-Mass Spectroscopy (GC-MS). Characterization of the catalyst showed that acidity was reduced because the Si/Al ratio was reduced after the impregnation and the surface area of Al-MCM-41/ceramics also decreased. SEM EDX shows that the composition of the carbon element on the surface of the Pd/Al- MCM-41/ceramic catalyst is smaller compared to the Al-MCM-41/ceramic catalyst. The results of the GC-MS characterization of liquid fuels from catalytic cracking using Pd/Al- MCM-41/ceramics catalyst, have a percentage of gasoline fraction (C7-C12) of 74.9% at 120 minutes cracking. The mixture of fuel from the addition of 150 mL liquid fuel resulting from catalytic cracking with Pd/Al-MCM-41/ceramic catalyst has the highest calorific value of 19160.61 (kcal/kg) and the performance of the gasoline Genset engine has the highest thermal efficiency of 28.27%.
UR - http://www.scopus.com/inward/record.url?scp=85083231735&partnerID=8YFLogxK
U2 - 10.1088/1755-1315/456/1/012006
DO - 10.1088/1755-1315/456/1/012006
M3 - Conference article
AN - SCOPUS:85083231735
SN - 1755-1307
VL - 456
JO - IOP Conference Series: Earth and Environmental Science
JF - IOP Conference Series: Earth and Environmental Science
IS - 1
M1 - 012006
T2 - 10th International Conference on Green Technology: Empowering the Fourth Industrial Revolution through Green Science and Technology, ICGT 2019
Y2 - 2 October 2019 through 3 October 2019
ER -